Stability and Rupture of an Ultrathin Ionic Wire.
Phys Rev Lett
; 129(4): 046101, 2022 Jul 22.
Article
em En
| MEDLINE
| ID: mdl-35939018
ABSTRACT
Using a combination of in situ high-resolution transmission electron microscopy and density functional theory, we report the formation and rupture of ZrO_{2} atomic ionic wires. Near rupture, under tensile stress, the system favors the spontaneous formation of oxygen vacancies, a critical step in the formation of the monatomic bridge. In this length scale, vacancies provide ductilelike behavior, an unexpected mechanical behavior for ionic systems. Our results add an ionic compound to the very selective list of materials that can form monatomic wires and they contribute to the fundamental understanding of the mechanical properties of ceramic materials at the nanoscale.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article