A General Strategy for the Asymmetric Preparation of &#945;-Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride- and Palladium-Catalysis.

Levi Knippel, James; Ni, Anton Z; Schuppe, Alexander W; Buchwald, Stephen L

A General Strategy for the Asymmetric Preparation of α-Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride- and Palladium-Catalysis.

Levi Knippel, James; Ni, Anton Z; Schuppe, Alexander W; Buchwald, Stephen L.

Afiliação

Levi Knippel J; Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, MA 02139, USA.
Ni AZ; Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, MA 02139, USA.
Schuppe AW; Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, MA 02139, USA.
Buchwald SL; Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, MA 02139, USA.

Angew Chem Int Ed Engl ; 61(47): e202212630, 2022 11 21.

Article em En | MEDLINE | ID: mdl-36137941

Assuntos

Metaloides; Paládio; Silanos; Cobre; Ésteres; Estereoisomerismo; Estrutura Molecular; Catálise

Palavras-chave

Allyl Boronate Ester; Allyl Metalloids; Allyl Silane; Asymmetric Catalysis; Copper Hydride

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Paládio / Metaloides Idioma: En Ano de publicação: 2022 Tipo de documento: Article

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