Improving the photovoltaic performance of inverted perovskite solar cells via manipulating the molecular packing structure of PCBM.
Nanotechnology
; 34(1)2022 Oct 17.
Article
em En
| MEDLINE
| ID: mdl-36174453
ABSTRACT
In this study, the molecular packing structure of solution-processed phenyl-C61-butyric acid methyl ester (PCBM) thin film was manipulated by varying the volume ratio of chlorobenzene (CB) to bromobenzene (BrB) from 1000 to 5050, which largely influences the device performance of the PCBM/perovskite heterojunction solar cells. Absorbance spectra, photoluminescence spectra, atomic force microscopic images and contact angle images were used to investigate the molecular packing structure effects of the PCBM thin films on the device performance of the inverted perovskite solar cells. Our experimental results show that the formation of PCBM aggregates and the contact quality at the PCBM/perovksite interface significantly influence the open-circuit voltage, short-circuit current density and fill factor of the resultant solar cells simultaneously. It is noted that the PCE of the encapsulated inverted CH3NH3PbI3(MAPbI3) solar cells exhibited a stable and high power conversion efficiency of 18%.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article