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Tunable cyano substituents in D-A conjugated polymers accessed via direct arylation for photocatalytic hydrogen production.
Ye, Dong-Nai; Zhang, Yu-Jie; Tan, Zhi-Rong; Xing, Yu-Qin; Chen, Zhengwang; Qiu, Jia-Bin; Liu, Shi-Yong.
Afiliação
  • Ye DN; Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, P. R. China. chelsy@zju.edu.cn.
  • Zhang YJ; School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, 341000, P. R. China.
  • Tan ZR; Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, P. R. China. chelsy@zju.edu.cn.
  • Xing YQ; Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, P. R. China. chelsy@zju.edu.cn.
  • Chen Z; Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, P. R. China. chelsy@zju.edu.cn.
  • Qiu JB; School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, 341000, P. R. China.
  • Liu SY; Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou, 341000, P. R. China. chelsy@zju.edu.cn.
Chem Commun (Camb) ; 58(91): 12680-12683, 2022 Nov 15.
Article em En | MEDLINE | ID: mdl-36286612
ABSTRACT
2-Styrylthiophene-based donor-acceptor linear conjugated polymers with tunable cyano substituents are atom-economically obtained via direct C-H arylation for platinum-free photocatalytic hydrogen production, affording a HER of up to 9.79 mmol h-1 g-1.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article