Amorphous Mo-doped NiS0.5 Se0.5 Nanosheets@Crystalline NiS0.5 Se0.5 Nanorods for High Current-density Electrocatalytic Water Splitting in Neutral Media.
Angew Chem Int Ed Engl
; 62(6): e202215256, 2023 Feb 01.
Article
em En
| MEDLINE
| ID: mdl-36461715
ABSTRACT
It is vitally important to develop highly active, robust and low-cost transition metal-based electrocatalysts for overall water splitting in neutral solution especially at large current density. In this work, amorphous Mo-doped NiS0.5 Se0.5 nanosheets@crystalline NiS0.5 Se0.5 nanorods (Am-Mo-NiS0.5 Se0.5 ) was synthesized using a facil one-step strategy. In phosphate buffer saline solution, the Am-Mo-NiS0.5 Se0.5 shows tiny overpotentials of 48 and 209â
mV for hydrogen evolution reaction (HER), 238 and 514â
mV for oxygen evolution reaction (OER) at 10 and 1000â
mA cm-2 , respectively. Moreover, Am-Mo-NiS0.5 Se0.5 delivers excellent stability for at least 300â
h without obvious degradation. Theoretical calculations revealed that the Ni sites in the defect-rich amorphous structure of Am-Mo-NiS0.5 Se0.5 owns higher electron state density and strengthened the binding energy of H2 O, which will optimize H adsorption/desorption energy barriers and reduce the adsorption energy of OER determining step.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article