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Accessing Chiral Pyrrolodiketopiperazines under Organocatalytic Conditions.
Duñabeitia, Eider; Landa, Aitor; López, Rosa; Palomo, Claudio.
Afiliação
  • Duñabeitia E; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country (UPV-EHU), Manuel de Lardizabal 3, 20018 San Sebastián, Spain.
  • Landa A; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country (UPV-EHU), Manuel de Lardizabal 3, 20018 San Sebastián, Spain.
  • López R; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country (UPV-EHU), Manuel de Lardizabal 3, 20018 San Sebastián, Spain.
  • Palomo C; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country (UPV-EHU), Manuel de Lardizabal 3, 20018 San Sebastián, Spain.
Org Lett ; 25(1): 125-129, 2023 01 13.
Article em En | MEDLINE | ID: mdl-36579971
ABSTRACT
The production of chiral pyrrolodiketopiperazines under organocatalytic conditions demonstrates the capacity of bicyclic acylpyrrol lactims to perform as pronucleophiles in direct carbon-carbon bond forming reactions. The good performance of ureidoaminal-derived Brønsted bases in the Michael addition to nitroolefins affords these heterocyclic scaffolds with high skeleton diversity.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Carbono Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Carbono Idioma: En Ano de publicação: 2023 Tipo de documento: Article