Light Alters the NH3 vs N2 H4 Product Profile in Iron-catalyzed Nitrogen Reduction via Dual Reactivity from an Iron Hydrazido (Fe=NNH2 ) Intermediate.

Garrido-Barros, Pablo; Chalkley, Matthew J; Peters, Jonas C

Light Alters the NH₃ vs N₂ H₄ Product Profile in Iron-catalyzed Nitrogen Reduction via Dual Reactivity from an Iron Hydrazido (Fe=NNH₂ ) Intermediate.

Garrido-Barros, Pablo; Chalkley, Matthew J; Peters, Jonas C.

Afiliação

Garrido-Barros P; Division of Chemistry and Chemical Engineering, California Institute of Technology (Caltech), 1200 E California Blvd, Pasadena, CA-91125, USA.
Chalkley MJ; Division of Chemistry and Chemical Engineering, California Institute of Technology (Caltech), 1200 E California Blvd, Pasadena, CA-91125, USA.
Peters JC; Division of Chemistry and Chemical Engineering, California Institute of Technology (Caltech), 1200 E California Blvd, Pasadena, CA-91125, USA.

Angew Chem Int Ed Engl ; 62(9): e202216693, 2023 Feb 20.

Article em En | MEDLINE | ID: mdl-36592374

Palavras-chave

Fe-Mediated N2R; Hydrazido Intermediate; Hydrazine Synthesis; Light-Controlled Selectivity; Nitrogen Fixation

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article