Decorating polymer beads with 1014 inorganic-organic [2]rotaxanes as shown by spin counting.
Commun Chem
; 5(1): 73, 2022 Jun 20.
Article
em En
| MEDLINE
| ID: mdl-36697699
ABSTRACT
Polymer beads have been used as the core of magnetic particles for around twenty years. Here we report studies to attach polymetallic complexes to polymer beads for the first time, producing beads of around 115 microns diameter that are attached to 1014 hybrid inorganic-organic [2]rotaxanes. The bead is then formally a [1014] rotaxane. The number of complexes attached is counted by EPR spectroscopy after including TEMPO radicals within the thread of the hybrid [2]rotaxanes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article