Structural insight into the magnesium borohydride - ethylenediamine solid-state Mg-ion electrolyte system.
Dalton Trans
; 52(8): 2404-2411, 2023 Feb 21.
Article
em En
| MEDLINE
| ID: mdl-36723231
ABSTRACT
A highly complex crystal structure of stoichiometric Mg5(en)6(BH4)10 was solved from single crystal synchrotron X-ray diffraction and confirmed by neutron powder diffraction (NPD) on isotopically substituted Mg(en)1.2(11BD4)2. We highlight the role of the amorphous Mg(BH4)2 in the reactivity of the Mg(BH4)2-en system and characterized a previously overlooked phase, Mg(en)2(BH4)2.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article