Crystal structure of barium dinickel(II) iron(III) tris-[orthophosphate(V)], BaNi2Fe(PO4)3.
Acta Crystallogr E Crystallogr Commun
; 79(Pt 2): 95-98, 2023 Jan 01.
Article
em En
| MEDLINE
| ID: mdl-36793405
ABSTRACT
The orthophosphate BaNi2Fe(PO4)3 has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni2O10] dimers that are linked to two PO4 tetra-hedra via common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO6] octa-hedra and [PO4] tetra-hedra. The linkage of the sheets and chains into a framework is accomplished through common vertices of PO4 tetra-hedra and [FeO6] octa-hedra. The framework is perforated by channels in which positionally disordered Ba2+ cations are located.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article