Your browser doesn't support javascript.
loading
Cationic ring-opening polymerization of N-benzylaziridines to polyamines via organic boron.
Gu, Ge-Ge; Yue, Tian-Jun; Ren, Wei-Min.
Afiliação
  • Gu GG; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials Oriented Chemical Engineering, Dalian University of Technology, Dalian 116024, China. wmren@dlut.edu.cn.
  • Yue TJ; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials Oriented Chemical Engineering, Dalian University of Technology, Dalian 116024, China. wmren@dlut.edu.cn.
  • Ren WM; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials Oriented Chemical Engineering, Dalian University of Technology, Dalian 116024, China. wmren@dlut.edu.cn.
Chem Commun (Camb) ; 59(20): 2982-2985, 2023 Mar 07.
Article em En | MEDLINE | ID: mdl-36807693
This communication reports the synthesis of cyclic polyamines via the cationic ring-opening polymerization (CROP) of N-benzylaziridines initiated by tris(pentafluorophenyl)borane. The debenzylation of these polyamines afforded water-soluble polyethylenimine derivatives. The electrospray ionization mass spectrometry and density functional theory results revealed that the CROP proceeded via the activated chain end intermediates.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article