Construction of amino-thiol functionalized ion-imprinted chitosan for lead (II) ion removal.

Ion-imprinting technique was used to create a lead ion-imprinted sorbent from an amino-thiol chitosan derivative (Pb-ATCS). First, 3-Nitro-4-sulfanylbenzoic acid (NSB) unit's amidized the chitosan, and then the -NO2-residues were selectively reduced to -NH2. Imprinting was accomplished by cross-linking with epichlorohydrin and removing the Pb (II) ions from the across-linked polymeric complex formed from the amino-thiol chitosan polymer ligand (ATCS) and Pb (II) ions. The synthetic steps have been investigated by nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR), and the sorbent was tested for its ability to selectively bind Pb (II) ions. The produced Pb-ATCS sorbent had a maximum capacity of roughly 300 mg/g, and it showed a greater affinity for the Pb (II) ions than the control NI-ATCS sorbent particle. The pseudo-2nd-order equation was also consistent with the adsorption kinetics of the sorbent, which were quite rapid. This demonstrated that metal ions were chemo-adsorbed onto the Pb-ATCS and NI-ATCS solid surfaces via coordination with the introduced amino-thiol moieties.