Significant Control on Zero-Field Quantum Tunneling of Magnetization in Dysprosium Based Single-Molecule Magnets via Orientation of the Anilato Ligand.
Chemistry
; 29(29): e202203664, 2023 May 22.
Article
em En
| MEDLINE
| ID: mdl-36877587
ABSTRACT
Tuning the bridging fashion of anilato ligand in dinuclear DyIII complexes, reveals a sizable effect on the slow relaxation of magnetization. Combined experimental and theoretical studies divulge that the geometry with high order axial symmetry (pseudo square antiprism) reduces the transverse crystal fields corresponding to QTM (quantum tunneling of magnetization) resulting in a significant increase in energy barrier (Ueff =518â
cm-1 ) through the Orbach relaxation process whereas the geometry with lower symmetry (triangular dodecahedron, pseudo D2d ) enhances the transverse crystal fields that accelerate the ground state QTM process. Notably, the value 518â
cm-1 represents the highest energy barrier among anilato ligand based SMMs.
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MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article