Stereodivergent Construction of [5,5]-Oxaspirolactones of Phainanoids.
J Org Chem
; 88(6): 3987-3991, 2023 Mar 17.
Article
em En
| MEDLINE
| ID: mdl-36883240
ABSTRACT
A stereodivergent synthesis of [5,5]-oxaspirolactones of phainanoids is presented herein. Through precisely tuning the inherent substitution differences on cyclopropanol, a palladium-catalyzed cascade carbonylative lactonization enables the stereodivergent synthesis of [5,5]-oxaspirolactones of phainanoids.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article