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Intrinsically Chiral Twist-Bend Nematogens: Interplay of Molecular and Structural Chirality in the NTB Phase.
Walker, Rebecca; Pociecha, Damian; Salamonczyk, Miroslaw; Storey, John M D; Gorecka, Ewa; Imrie, Corrie T.
Afiliação
  • Walker R; Department of Chemistry, School of Natural and Computing Sciences, University of Aberdeen, Meston Building, AB24 3UE, Aberdeen, UK.
  • Pociecha D; Faculty of Chemistry, University of Warsaw, ul. Zwirki i Wigury 101, 02-089, Warsaw, Poland.
  • Salamonczyk M; Faculty of Chemistry, University of Warsaw, ul. Zwirki i Wigury 101, 02-089, Warsaw, Poland.
  • Storey JMD; Department of Chemistry, School of Natural and Computing Sciences, University of Aberdeen, Meston Building, AB24 3UE, Aberdeen, UK.
  • Gorecka E; Faculty of Chemistry, University of Warsaw, ul. Zwirki i Wigury 101, 02-089, Warsaw, Poland.
  • Imrie CT; Department of Chemistry, School of Natural and Computing Sciences, University of Aberdeen, Meston Building, AB24 3UE, Aberdeen, UK.
Chemphyschem ; 24(6): e202300105, 2023 Mar 14.
Article em En | MEDLINE | ID: mdl-36916801
The front cover artwork is provided by Dr Rebecca Walker of the Liquid Crystals Group at the University of Aberdeen. The image is a cartoon depiction of the formation of the heliconical chiral twist-bend nematic phase (N*TB ) from its constituent bent molecules. The presence of a single enantiomer of the chiral, lactate-based liquid crystal dimers biases the formation of helices with only one handedness, unlike in the conventional NTB phase, observed for achiral molecules, for which the left- and right-handed helices are doubly degenerate. Read the full text of the Research Article at 10.1002/cphc.202200807.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article