Photocatalytic synthesis of alkyl-alkyl sulfones via direct C(sp3)-H bond functionalization.
Org Biomol Chem
; 21(13): 2822-2827, 2023 Mar 29.
Article
em En
| MEDLINE
| ID: mdl-36928523
ABSTRACT
We report a highly efficient one-pot, three-component strategy for the construction of alkyl-alkyl sulfones through a photoinduced TBADT-catalyzed C(sp3)-H sulfonylation of unactivated hydrocarbon compounds. A wide range of commercially available hydrocarbon compounds and bioactive molecules can be successfully applied to the catalytic system, affording the corresponding alkyl-alkyl sulfones in good to excellent yields (>50 examples, up to 87% yield).
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article