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Improper ferroelastic phase transition in a hydrogen-bonded metallocyanide-based (azetidinium)2(H3O)[Co(CN)6] framework.
Moskwa, Marcin; Sobieszczyk, Pawel; Mikurenda, Julia W; Zielinski, Piotr; Rok, Magdalena.
Afiliação
  • Moskwa M; Faculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, Wroclaw 50-383, Poland. marcin.moskwa@uwr.edu.pl.
  • Sobieszczyk P; The H. Niewodniczanski Institute of Nuclear Physics PAS, Radzikowskiego 152, Kraków 31-342, Poland.
  • Mikurenda JW; Faculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, Wroclaw 50-383, Poland. marcin.moskwa@uwr.edu.pl.
  • Zielinski P; The H. Niewodniczanski Institute of Nuclear Physics PAS, Radzikowskiego 152, Kraków 31-342, Poland.
  • Rok M; Faculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, Wroclaw 50-383, Poland. marcin.moskwa@uwr.edu.pl.
Chem Commun (Camb) ; 59(37): 5535-5538, 2023 May 04.
Article em En | MEDLINE | ID: mdl-37038752
ABSTRACT
A hydrogen-bonded metallocyanide-based (AZE)2(H3O)[Co(CN)6] framework was obtained by introducing a hydronium cation to the A2B(1)B(2)CN6-type structure. Simple K+/H3O+ substitution exchange the three-dimensional structure of the double-perovskite into two-dimensional layers containing open inorganic cages with a strongly discontinuous improper ferroelastic phase transition.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article