Improper ferroelastic phase transition in a hydrogen-bonded metallocyanide-based (azetidinium)2(H3O)[Co(CN)6] framework.
Chem Commun (Camb)
; 59(37): 5535-5538, 2023 May 04.
Article
em En
| MEDLINE
| ID: mdl-37038752
ABSTRACT
A hydrogen-bonded metallocyanide-based (AZE)2(H3O)[Co(CN)6] framework was obtained by introducing a hydronium cation to the A2B(1)B(2)CN6-type structure. Simple K+/H3O+ substitution exchange the three-dimensional structure of the double-perovskite into two-dimensional layers containing open inorganic cages with a strongly discontinuous improper ferroelastic phase transition.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article