Complexities in the structural evolution with pressure of water-ammonia mixtures.
J Chem Phys
; 158(18)2023 May 14.
Article
em En
| MEDLINE
| ID: mdl-37154278
ABSTRACT
The structural evolution with pressure of icy mixtures of simple molecules is a poorly explored field despite the fundamental role they play in setting the properties of the crustal icy layer of the outer planets and of their satellites. Water and ammonia are the two major components of these mixtures, and the crystal properties of the two pure systems and of their compounds have been studied at high pressures in a certain detail. On the contrary, the study of their heterogeneous crystalline mixtures whose properties, due to the strong N-Hâ¯O and O-Hâ¯N hydrogen bonds, can be substantially altered with respect to the individual species has so far been overlooked. In this work, we performed a comparative Raman study with a high spatial resolution of the lattice phonon spectrum of both pure ammonia and water-ammonia mixtures in a pressure range of great interest for modeling the properties of icy planets' interiors. Lattice phonon spectra represent the spectroscopic signature of the molecular crystals' structure. The activation of a phonon mode in plastic NH3-III attests to a progressive reduction in the orientational disorder, which corresponds to a site symmetry reduction. This spectroscopic hallmark allowed us to solve the pressure evolution of H2O-NH3-AHH (ammonia hemihydrate) solid mixtures, which present a remarkably different behavior from the pure crystals likely to be ascribed to the role of the strong H-bonds between water and ammonia molecules characterizing the crystallites' surface.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article