Metal-organic frameworks (MOFs) composite of polyaniline-CNT@aluminum succinate for non-enzymatic nitrite sensor.

ABSTRACT

Nitrite has been linked to a variety of health issues, as well as cancer and oxygen deficiency when its allowable limit is exceeded. Nitrite monitoring and detection are required due to the negative effects on public health. Metal-organic frameworks (MOFs)-based nanomaterials/composites have recently been shown to have the potential for various biological and medical applications like sensing, imaging, and drug delivery. As a result, this research creates an efficient electrochemical sensor by incorporating MOFs into polyaniline (PANI)/carbon nanotube (CNT) cast on the GCE. In situ oxidative polymerization was used to construct an aluminum succinate MOF (Al-Succin)-incorporated CNT/PANI nanocomposite (PANI/CNT@Al-Succin) and well characterized by various characterization techniques, namely, field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric-differential thermal analysis (TGA-DTA), cyclic voltammetry (CV), and four probes to measure DC electrical conductivity. Cyclic voltammetry and linear sweep voltammetry techniques were employed to detect nitrite on the surface of PANI/CNT@Al-Succin-modified glassy carbon electrode (GCE). PANI/CNT@Al-Succin-modified GCE demonstrated good current response and electrocatalytic property towards nitrite compared to bare GCE. The newly synthesized electrode exhibited a high electrocatalytic activity towards nitrite oxidation and showed a linear response ranging from 5.7 to 74.1 µM for CV and 8.55-92.62 µM for LSV. The obtained LOD values for CV (1.16 µM) and LSV (0.08 µM) were significantly below the WHO-defined acceptable nitrite limit in drinking water. Results of recovery studies for real samples of apple juice, orange juice, and bottled water were 98.92%, 99.38%, and 99.90%, respectively. These values show practical usability of PANI/CNT@Al-Succin in real samples.