Sensitive 1,4-Disubstituted Nitro-Containing Cubanes: Structures and Properties.
J Org Chem
; 88(18): 12884-12890, 2023 Sep 15.
Article
em En
| MEDLINE
| ID: mdl-37616479
ABSTRACT
The cubane cage system is characteristic and well known for its high strain energy, qualifying it as a promising precursor for energetic materials. 1,4-Disubstituted cubanes are the easiest accessible derivatives. A further developed laboratory-scale procedure for cubane-1,4-dicarboxylic acid dimethyl ester is presented. From this central precursor, the bis-trinitroethyl and bis-nitromethyl esters as well as the bis-methylcarbamate and bis-methylnitrocarbamate were synthesized and characterized by multinuclear NMR spectroscopy and X-ray crystallography. In addition, their physical and energetic properties were determined and studied.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Diagnostic_studies
País/Região como assunto:
Cuba
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article