Kagome-topology 2D covalent organic frameworks assembled from D2h-symmetric and non-centrosymmetric C2-symmetric blocks for photothermal imaging.
Chem Commun (Camb)
; 59(88): 13191-13194, 2023 Nov 02.
Article
em En
| MEDLINE
| ID: mdl-37850458
ABSTRACT
In this study, we synthesized two new two-dimensional (2D) covalent organic frameworks (COFs), COF-TA and COF-DP, by combining 4-connected D2h-symmetric and 2-connected non-centrosymmetric C2-symmetric building blocks. Unlike the typical sql topology, these COFs exhibit an unconventional kgm topology characterized by a favorable anti-parallel stacking arrangement, which results in a lower energy configuration. Notably, COF-DP, with its unique D-A-D structural motif and photosensitive properties, demonstrates a narrow band gap and excellent photothermal conversion capabilities, making it a promising material for photothermal imaging applications.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article