Using a molecular additive to control chiral supramolecular assembly and the subsequent chirality transfer process.

ABSTRACT

Hierarchical assembly of chiral molecules is achieved through the introduction of molecular additives, which enables the chiral assembly of nanosheets into helical nanorods with inverted chirality. Moreover, the hierarchical assembly of chiral molecules in the presence of a molecular additive can lead to the subsequent chirality transfer from a molecular system to nanoparticle assemblies.