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Recent Progress on Phase Engineering of Nanomaterials.
Yun, Qinbai; Ge, Yiyao; Shi, Zhenyu; Liu, Jiawei; Wang, Xixi; Zhang, An; Huang, Biao; Yao, Yao; Luo, Qinxin; Zhai, Li; Ge, Jingjie; Peng, Yongwu; Gong, Chengtao; Zhao, Meiting; Qin, Yutian; Ma, Chen; Wang, Gang; Wa, Qingbo; Zhou, Xichen; Li, Zijian; Li, Siyuan; Zhai, Wei; Yang, Hua; Ren, Yi; Wang, Yongji; Li, Lujing; Ruan, Xinyang; Wu, Yuxuan; Chen, Bo; Lu, Qipeng; Lai, Zhuangchai; He, Qiyuan; Huang, Xiao; Chen, Ye; Zhang, Hua.
Afiliação
  • Yun Q; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Ge Y; Department of Chemical and Biological Engineering & Energy Institute, The Hong Kong University of Science and Technology, Hong Kong, China.
  • Shi Z; School of Materials Science and Engineering, Peking University, Beijing 100871, China.
  • Liu J; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Wang X; Institute of Sustainability for Chemicals, Energy and Environment, Agency for Science, Technology and Research (A*STAR), Singapore, 627833, Singapore.
  • Zhang A; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Huang B; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Yao Y; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Luo Q; Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM), City University of Hong Kong, Hong Kong, China.
  • Zhai L; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Ge J; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Peng Y; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Gong C; Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM), City University of Hong Kong, Hong Kong, China.
  • Zhao M; Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR.
  • Qin Y; College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Ma C; College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Wang G; Institute of Molecular Aggregation Science, Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin 300072, China.
  • Wa Q; Institute of Molecular Aggregation Science, Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin 300072, China.
  • Zhou X; Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong, China.
  • Li Z; Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong, China.
  • Li S; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Zhai W; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Yang H; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Ren Y; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Wang Y; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Li L; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Ruan X; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Wu Y; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Chen B; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Lu Q; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • Lai Z; Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
  • He Q; State Key Laboratory of Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials, School of Chemistry and Life Sciences, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
  • Huang X; School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Chen Y; Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong SAR, China.
  • Zhang H; Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, China.
Chem Rev ; 123(23): 13489-13692, 2023 Dec 13.
Article em En | MEDLINE | ID: mdl-37962496
As a key structural parameter, phase depicts the arrangement of atoms in materials. Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the development of nanotechnology, nanomaterials with unconventional crystal phases, which rarely exist in their bulk counterparts, or amorphous phase have been prepared using carefully controlled reaction conditions. Together these methods are beginning to enable phase engineering of nanomaterials (PEN), i.e., the synthesis of nanomaterials with unconventional phases and the transformation between different phases, to obtain desired properties and functions. This Review summarizes the research progress in the field of PEN. First, we present representative strategies for the direct synthesis of unconventional phases and modulation of phase transformation in diverse kinds of nanomaterials. We cover the synthesis of nanomaterials ranging from metal nanostructures such as Au, Ag, Cu, Pd, and Ru, and their alloys; metal oxides, borides, and carbides; to transition metal dichalcogenides (TMDs) and 2D layered materials. We review synthesis and growth methods ranging from wet-chemical reduction and seed-mediated epitaxial growth to chemical vapor deposition (CVD), high pressure phase transformation, and electron and ion-beam irradiation. After that, we summarize the significant influence of phase on the various properties of unconventional-phase nanomaterials. We also discuss the potential applications of the developed unconventional-phase nanomaterials in different areas including catalysis, electrochemical energy storage (batteries and supercapacitors), solar cells, optoelectronics, and sensing. Finally, we discuss existing challenges and future research directions in PEN.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article