Porphyrin-Based Metal-Organic Framework Materials: Design, Construction, and Application in the Field of Photocatalysis.

ABSTRACT

Metal-organic frameworks (MOFs) are a novel category of porous crystalline materials with an exceptionally high surface area and adjustable pore structure. They possess a designable composition and can be easily functionalized with different units. Porphyrins with conjugated tetrapyrrole macrocyclic structures can absorb light from ultraviolet to visible light regions, and their structures and properties can be facilely regulated by altering their peripheral groups or central metal ions. Porphyrin-based MOFs constructed from porphyrin ligands and metal nodes combine the unique features of porphyrins and MOFs as well as overcoming their respective limitations. This paper reviewed the design and construction, light absorption and charge transfer pathways, and strategy for improving the photocatalytic performance of porphyrin-based MOFs, and highlighted the recent progress in the field of CO2 reduction, hydrogen evolution, organic synthesis, organic pollutant removal, and nitrogen fixation. The intrinsic relationships between the structure and the property of porphyrin-based MOFs received special attention, especially the relationships between the arrangements of porphyrin ligands and metal nods and the charge transfer mechanism. We attempted to provide more valuable information for the design and construction of advanced photocatalysts in the future. Finally, the challenges and future perspectives of the porphyrin-based MOFs are also discussed.