Abiotic weathering of plastic: Experimental contributions towards understanding the formation of microplastics and other plastic related particulate pollutants.

ABSTRACT

The increasing use of plastic (synthetic polymers) results in the release of uncontrollable amounts of synthetic materials into the environment through waste, infrastructure, and essential goods. As plastic materials undergo weathering, a complex process unfolds, leading to the formation of pollutants, notably microplastics. This study employs multiple instrumental methods to explore the intricate abiotic degradation of the five most commonly used synthetic polymers in environmentally relevant conditions. An extensive set of analytical techniques, along with chemometric analysis of the results of Raman spectroscopy, was used to characterize the materials and evaluate the nature and extent of degradation caused by artificial weathering under temperature, humidity, and solar-like irradiation cycles. Investigation focuses on the link between abiotic weathering and the generation of micro- and nanoplastics, accompanied by molecular and surface adhesion changes, and the release of additives such as metals and metal oxides. Research reveals that microplastics may exhibit varied physical properties due to the incorporation of significant quantities of high-density additives from the parent plastic, which might influence the extraction methods and the transportation models' accuracy. At the molecular and microscopic scales, non-homogeneous pathways through which plastic decomposes during weathering were observed. The formation of additive-polymer combinations might play a pivotal role in the monitoring approaches for microplastics, presenting unique challenges in assessing the environmental impact of different plastic types. These findings offer complex insight into abiotic weathering, microplastics' generation, and the influence of additives that were previously overlooked in toxicity and health assessment studies. As plastic pollution continues to escalate, understanding these complex processes is crucial for microplastic monitoring development and adopting effective preventative measures.