Boron Nitride Nanosheet-Magnetic Nanoparticle Composites for Water Remediation Applications.

ABSTRACT

The combination of 0D nanoparticles with 2D nanomaterials has attracted a lot of attention over the last years due to the unique multimodal properties of resulting 0D-2D nanocomposites. In this work, we developed boron nitride nanosheets (BNNS) functionalized with manganese ferrite magnetic nanoparticles (MNPs). The functionalization process involved attachment of MNPs to exfoliated BNNS by refluxing the precursor materials in a polyol medium. Characterization of the produced BNNS-MNP composites was carried out using powder X-ray diffraction, transmission electron microscopy, vibrating sample magnetometry, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The adhesion of MnFe2O4 magnetic nanoparticles onto the BNNS remained unaffected by repeated sonication and heating in a furnace at 400 °C, underscoring the robust nature of the formed bond. FTIR spectra and XPS deconvolution confirmed the presence of strong bonding between BNNS and the MNPs. Membranes were fabricated from the BNNS and the BNNS-MnFe2O4 nanocomposites for evaluating their efficiency in removing the methylene blue dye pollutant. The membranes have been characterized by scanning electron microscopy, Brunauer-Emmett-Teller surface area analysis, and mercury intrusion porosimetry. The effectiveness of dye removal was monitored using ultraviolet-visible spectroscopy. The BNNS-MnFe2O4 nanocomposite membranes exhibited enhanced MB capture compared to membranes made from pure BNNS alone. The recyclability assessment of BNNS-MnFe2O4 demonstrated exceptional performance, retaining 92% efficiency even after eight cycles. These results clearly demonstrate the high potential of these magnetic nanocomposites as reusable materials for water filtration membranes. Furthermore, the introduction of magnetic functionality as part of the membrane brings an exciting opportunity for in situ magnetic heating of the membrane, which shall be explored in future work.