Diels-Alder cycloaddition polymerization for porous poly-phenylenes with exceptional gas uptake properties.
Chem Commun (Camb)
; 60(19): 2657-2660, 2024 Feb 29.
Article
em En
| MEDLINE
| ID: mdl-38348903
ABSTRACT
We report the synthesis of two-dimensional and three-dimensional porous polyphenylenes (2D/3D-pPPs) via the Diels-Alder cycloaddition polymerization reaction. The resulting 2D and 3D-pPPs showed surface areas up to 1553 m2 g-1, pore volumes of 1.45 cm3 g-1 and very high H2 uptake capacities of 7.4 and 7.1 wt% at 77 K, respectively, along with a competitive high-pressure CO2 and CH4 uptake performance.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article