The regulation of CuSNPs' interface for further enhancing mechanical and photothermal conversion properties of chitosan/@CuSNPs hybrid fibers.

ABSTRACT

Our previous study has demonstrated that the microstructure of copper sulfide nanoparticles (CuSNPs) can be controlled to enhance mechanical and photothermal conversion properties of chitosan (CS)/CuSNPs hybrid fibers. However, achieving optimal dispersion and compatibility of CuSNPs within a CS matrix remains a challenge, this study aims to improve dispersion and compatibility by modifying the CuSNPs' interface, thereby enhancing mechanical and photothermal conversion properties of hybrid fibers. The interfaces of @CuSNPs (CuS@Xylan NPs, CuS@SA NPs, and CuS@PEG NPs) contain hydroxyl groups, facilitating the hydrogen bonds formation with the CS matrix. The dispersibility is further enhanced by the synergistic effect of xylan and SA's anionic charges with cationic chitosan. Notably, the viscosity of the CS/@CuSNPs hybrid spinning solution is significantly enhanced, resulting in improved breaking strength for initial hybrid fibers. Specifically, the breaking strength of CS/CuS@Xylan NPs hybrid fibers reaches 1.4 cN/dtex, exhibiting a 42.86 % and 20.6 % increase over CS and CS/CuSNPs hybrid fibers. Simultaneously, the CS/CuS@Xylan NPs hybrid fibers exhibit exceptional photothermal conversion performance, surpassing that of CS fibers by 5.2 times and CS/CuSNPs hybrid fibers by 1.4 times. The regulation of interface modification is an efficient approach to enhance the tensile strength and photothermal conversion properties of CS/CuSNPs hybrid fibers.