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Novel cow dung-doped sludge biochar as an efficient ozone catalyst: Synergy between graphitic structure and defects induces free radical pathways.
Yang, Yuxuan; Ma, Kedong; Cui, Yubo; Zhao, Ke; Lu, Yuning; Zhang, Wanjun; Kuang, Peijing; Zou, Xuejun.
Afiliação
  • Yang Y; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China.
  • Ma K; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China. Electronic address: makedongdl@yahoo.co.
  • Cui Y; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China. Electronic address: cyb@dlnu.edu.cn.
  • Zhao K; Key Laboratory of Songliao Aquatic Environment, Ministry of Education, Jilin Jianzhu University, Changchun, 130118, People's Republic of China.
  • Lu Y; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China.
  • Zhang W; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China.
  • Kuang P; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China.
  • Zou X; Key Laboratory of Biotechnology and Bioresources Utilization, Ministry of Education, Dalian Minzu University, Dalian 116600, People's Republic of China; College of Environment and Resources, Dalian Minzu University, Dalian, 116600, People's Republic of China.
Environ Res ; 251(Pt 2): 118747, 2024 Jun 15.
Article em En | MEDLINE | ID: mdl-38527717
ABSTRACT
A composite material, cow dung-doped sludge biochar (Zn@SBC-CD), was synthesized by one-step pyrolysis using ZnCl2 as an activating agent and applied to a catalytic ozonation process (COP) for methylene blue (MB) removal. SEM, XRD, FTIR, XPS and BET analyses were performed to characterize the biochar (BC) catalysts. Zn@SBC-CD had high graphitization degree, abundant active sites and uniform distribution of Zn on its surface. Complete removal of MB was achieved within 10 min, with a removal rate much higher than that of ozone alone (32.4%), implying the excellent ozone activation performance of Zn@SBC-CD. The influence of experimental parameters on MB removal efficiency was examined. Under the optimum conditions in terms of ozone dose 0.04 mg/mL, catalyst dose 400 mg/L and pH 6.0, COD was completely removed after 20 min. Electron paramagnetic resonance (EPR) analysis revealed radical and non-radical pathways were involved in MB degradation. The Zn@SBC-CD/O3 system generated superoxide anion radicals (•O2-), which were the main active species for MB removal, through adsorption, transformation, and transfer, Furthermore, Zn@SBC-CD exhibited good reusability and stability in cycling experiments. This study provides a novel approach for the utilization of cow dung and sludge in synthesis of functional biocatalysts and application in organic wastewater treatment.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ozônio / Carvão Vegetal / Grafite Limite: Animals Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ozônio / Carvão Vegetal / Grafite Limite: Animals Idioma: En Ano de publicação: 2024 Tipo de documento: Article