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Light-Induced, Structural Matrix Guided Stepwise Spin-State Switching in 3d-5d Molecular Assembly.
Kaushik, Krishna; Sarkar, Archita; Kamilya, Sujit; Li, Yanling; Dechambenoit, Pierre; Rouzières, Mathieu; Mehta, Sakshi; Mondal, Abhishake.
Afiliação
  • Kaushik K; Solid State and Structural Chemistry Unit, Indian Institute of Science, Sir C V Raman Road, 560012 Bangalore, India.
  • Sarkar A; Solid State and Structural Chemistry Unit, Indian Institute of Science, Sir C V Raman Road, 560012 Bangalore, India.
  • Kamilya S; Solid State and Structural Chemistry Unit, Indian Institute of Science, Sir C V Raman Road, 560012 Bangalore, India.
  • Li Y; Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, Sorbonne Université, 4 place Jussieu, F-75252 Paris, cedex 5, France.
  • Dechambenoit P; Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, CRPP, UMR 5031, 33600 Pessac, France.
  • Rouzières M; Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, CRPP, UMR 5031, 33600 Pessac, France.
  • Mehta S; Solid State and Structural Chemistry Unit, Indian Institute of Science, Sir C V Raman Road, 560012 Bangalore, India.
  • Mondal A; Solid State and Structural Chemistry Unit, Indian Institute of Science, Sir C V Raman Road, 560012 Bangalore, India.
Inorg Chem ; 63(17): 7604-7612, 2024 Apr 29.
Article em En | MEDLINE | ID: mdl-38556753
ABSTRACT
A new iron(II) molecular complex {[W(CN)8][Fe(bik*)3]2}BF4·7H2O·1.5CH3OH (1.7H2O·1.5CH3OH) was synthesized using a versatile octacyanotungstate(V) building block and N-donor bidentate ligand (bik* = bis(1-ethyl-1H-imidazol-2-yl)ketone) and detailed characterizations were carried out. The crystal structure of 1.7H2O·1.5CH3OH is composed of an ionic salt from one anionic [W(CN)8]3- unit, two isolated cationic [Fe(bik*)3]2+ units, and one BF4- counteranion in the asymmetric unit. Magnetic studies of 1.7H2O·1.5CH3OH display interesting two-step reversible thermo-induced spin-state switching and the partially desolvated form 1.7H2O shows a photomagnetic effect at low temperatures. Additionally, the physical properties of 1.7H2O·1.5CH3OH were compared with the monomeric unit of {[Fe(bik*)3]2}·4ReO4·H2O (2.H2O) and detailed photophysical investigations were also performed to study the effect of a structural matrix {[W(CN)8]3- and ReO4- unit} on the spin-state switching properties of the [Fe(bik*)3]2+ unit in both systems (1.7H2O·1.5CH3OH and 2.H2O).

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article