Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono-, Tri-, and Tetrafunctionalized Hydrazines in Two Steps from N2.
J Am Chem Soc
; 2024 Apr 10.
Article
em En
| MEDLINE
| ID: mdl-38598273
ABSTRACT
The addition of chlorotrimethylsilane to a boron-mediated, transition-metal-free N2 activation reaction leads to the isolation of multiple potassium boryl(silyl)hydrazido species, likely trapping products of a terminal dinitrogen complex of boron. One of these silylated N2 species can be protonated or methylated, providing access to mono- to tetrafunctionalized hydrazines in two steps from N2 and in the absence of transition metals.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article