First total synthesis of asperilactone B. Revision of absolute stereochemistry of asperilactones B and C.
Org Biomol Chem
; 22(24): 4864-4867, 2024 Jun 19.
Article
em En
| MEDLINE
| ID: mdl-38747648
ABSTRACT
The first total synthesis and absolute configuration assignment of asperilactone B (I) have been accomplished. Additionally, a revision of the absolute stereochemistry of asperilactone C has been done. The first total synthesis of the opposite enantiomer of asperilactone B (ent-I) has also been achieved, as well as that of C-7 epimers of both asperilactones B (8) and C (9).
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article