The enrichment and transformation mechanism of Pb and Cu in suspension magnetization roasting and magnetic separation from iron tailings.

ABSTRACT

Magnetic iron concentrate (MIC) and nonmagnetic tailings (NT) are obtained from magnetization roasting of iron tailings (IT). MIC containing Pb adversely affects blast furnace ironmaking, while Cu in NT poses leaching risks. This study utilizes fast pyrolysis-suspension magnetization roasting to recover iron from IT. The enrichment of Pb, Cu, and the phase transformation mechanism of Cu in the process of suspension magnetization roasting and magnetic separation were clarified. Results show 96.13 % of Cu in IT is in limonite and 47.23 % of Pb is associated with iron. At 750 °C, with 10 % dosage of biomass pyrolysis and 10 min roasting, Pb, Cu and Fe contents in MIC are 0.96, 2.14 and 3.17 times that of NT. Increasing roasting temperature enhances Cu associated with iron enrichment into the MIC, while oxidation of free copper oxide associated with iron forms magnetic copper ferrite. Increased pyrolyzed biomass leads to over-reduction of magnetite associated with Cu to FeO associated with Cu, promoting magnetic copper ferrite decomposition into FeO and free copper oxide. This research holds significant importance in controlling the quality of MIC and the storage risk of IT, and provides theoretical guidance for the regulation and recovery of valuable metals in subsequent processes.