Time-resolved EPR observation of blue-light-induced radical ion pairs in a flavin-Trp dyad.
Phys Chem Chem Phys
; 26(23): 16444-16448, 2024 Jun 12.
Article
em En
| MEDLINE
| ID: mdl-38808575
ABSTRACT
A dyad of flavin and Trp bridged by a p-phenylamide linker was synthesized as an artificial model system to investigate molecular-based magnetic-field sensors relevant to blue-light photoreceptor proteins. The results demonstrated that intramolecular electron transfer generates a radical pair, only the triplet-born one of which has a microsecond lifetime at room temperature.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article