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A mononuclear Fe(III) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour.
Bridová, Terézia; Rajnák, Cyril; Titis, Ján; Samolová, Erika; Tran, Kevin; Malina, Ondréj; Bienko, Alina; Renz, Franz; Gembický, Milan; Boca, Roman.
Afiliação
  • Bridová T; Faculty of Natural Sciences, University of Ss. Cyril and Methodius, 917 01 Trnava, Slovakia. cyril.rajnak@ucm.sk.
  • Rajnák C; Faculty of Natural Sciences, University of Ss. Cyril and Methodius, 917 01 Trnava, Slovakia. cyril.rajnak@ucm.sk.
  • Titis J; Faculty of Natural Sciences, University of Ss. Cyril and Methodius, 917 01 Trnava, Slovakia. cyril.rajnak@ucm.sk.
  • Samolová E; Institute of Physics of the Czech Academy of Sciences, 182 21 Prague, Czech Republic.
  • Tran K; Institute of Inorganic Chemistry, Leibniz University, Hannover, D-30167, Germany.
  • Malina O; Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University Olomouc, Olomouc, Czech Republic.
  • Bienko A; Nanotechnology Centre, Centre of Energy and Environmental Technologies, VSB-Technical University of Ostrava, Ostrava-Poruba, Czech Republic.
  • Renz F; Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie, 50-383 Wroclaw, Poland.
  • Gembický M; Institute of Inorganic Chemistry, Leibniz University, Hannover, D-30167, Germany.
  • Boca R; X-ray Crystallography Facility, UC San Diego, 5128 Urey Hall MC 0358, 9500 Gilman Drive, La Jolla, CA 92093, USA.
Dalton Trans ; 53(26): 10824-10828, 2024 Jul 02.
Article em En | MEDLINE | ID: mdl-38887079
ABSTRACT
AC susceptibility measurements of [FeIII(L5)(NCSe)] reveal a field supported slow magnetic relaxation. On cooling, the relaxation time of the high-frequency fraction decreases which is a sign of reciprocating thermal behaviour. The relaxation time for the low-frequency mode at T = 2.0 K is as high as τ(LF) = 2.0 s.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article