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A near-infrared-II light-response BODIPY-based conjugated microporous polymer for enhanced photocatalytic degradation of cationic dyes and H2O2 production.
Luo, Xiaobo; Zhang, Yan; Zhou, Shiyuan; Wang, Peng; Wang, Danfeng; Gu, Peiyang.
Afiliação
  • Luo X; Engineering Laboratory of Functional Nano- and Microstructured Materials in Petroleum and Chemical Industry, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, P. R. China. gupeiyang0714@cczu.edu.cn.
  • Zhang Y; Engineering Laboratory of Functional Nano- and Microstructured Materials in Petroleum and Chemical Industry, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, P. R. China. gupeiyang0714@cczu.edu.cn.
  • Zhou S; Engineering Laboratory of Functional Nano- and Microstructured Materials in Petroleum and Chemical Industry, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, P. R. China. gupeiyang0714@cczu.edu.cn.
  • Wang P; College of Biological, Chemical Science and Chemical Engineering, Jiaxing University, Jiaxing 314001, China. pengwang@zjxu.edu.cn.
  • Wang D; Engineering Laboratory of Functional Nano- and Microstructured Materials in Petroleum and Chemical Industry, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, P. R. China. gupeiyang0714@cczu.edu.cn.
  • Gu P; State Key Laboratory of Treatments and Recycling for Organic Effluents by Adsorption in Petroleum and Chemical Industry, Soochow University, Suzhou, 215123, China.
Chem Commun (Camb) ; 60(61): 7910-7913, 2024 Jul 25.
Article em En | MEDLINE | ID: mdl-38980120
ABSTRACT
A BODIPY-containing conjugated microporous polymer (CMP, LBFD-1) was modified with calixarene to develop a hydrophilic CMP (LBFD-2) with broader absorption extending to the near-infrared-II region. LBFD-2 exhibited an H2O2 production rate of 2.14 mmol g-1 h-1 in the air without any sacrificial agents. The removal efficiency (η) of LBFD-2 towards methylene blue and rhodamine B reached >99.5% within 20 and 40 min in light. LBFD-2 can withstand diverse environmental changes, showing excellent reusability and potential for practical applications in real-water systems.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article