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Two 2D spin-crossover coordination polymers constructed by [Pd(SCN)4]2- building blocks.
Xie, Kai-Ping; Peng, Zhi-Zhen; Ruan, Ze-Yu; Fan, Wei-Ding; Chen, Yan-Ru; Zheng, Xiao-Dan; Zou, Yu-Bo; Wu, Si-Guo; Xiao, Zi-Cheng.
Afiliação
  • Xie KP; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
  • Peng ZZ; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
  • Ruan ZY; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun, Yat-Sen University, Guangzhou, 510275, P. R. China. wusg6@mail.sysu.edu.cn.
  • Fan WD; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
  • Chen YR; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun, Yat-Sen University, Guangzhou, 510275, P. R. China. wusg6@mail.sysu.edu.cn.
  • Zheng XD; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
  • Zou YB; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
  • Wu SG; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun, Yat-Sen University, Guangzhou, 510275, P. R. China. wusg6@mail.sysu.edu.cn.
  • Xiao ZC; School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, P. R. China. xiekp@hzu.edu.cn.
Dalton Trans ; 2024 Sep 09.
Article em En | MEDLINE | ID: mdl-39248579
ABSTRACT
Two new two-dimensional (2D) coordination polymers, [FeII(L)2{PdII(SCN)4}] (L1 = 2-methoxypyrazine, 1; and L2 = (E)-3-(phenyldiazenyl)pyridine, 2), were successfully constructed by using square-planar [Pd(SCN)4]2- building blocks. Complex 1 exhibits complete and one-step spin-crossover (SCO) behavior, while 2 exhibits incomplete and two-step SCO behavior. Further structural insight into this synergy reveals that the flat/flexing [Fe{Pd(SCN)4}]∞ sheets in 1 and 2 are stabilized by interlayered/intralayered supramolecular interactions.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article