Structural analysis of hexa to dodecaoligosaccharide-alditols released by reductive beta-elimination from oviducal mucins of Bufo bufo.
Glycobiology
; 7(8): 1129-51, 1997 Dec.
Article
em En
| MEDLINE
| ID: mdl-9455914
ABSTRACT
Hexa to dodecasaccharide-alditols of the jelly coat surrounding the eggs of the toad Bufo bufo were studied by methylation analysis, MALDI-TOF mass spectrometry, and H-NMR spectroscopy. These highly species-specific carbohydrate chains exhibit new structural features, such as the elongation of the blood group A determinant with an external alpha-1,3-linked galactose unit, or ramification belonging from a fucosylated galactose. The most representative oligosaccharide-alditol of the series was defined as following [structure in text]. Since the jellies surrounding amphibian eggs are involved in egg-sperm interactions, these structural investigations can provide biochemical support for exploring the fertilization process.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Oligossacarídeos
/
Álcoois Açúcares
/
Bufo bufo
/
Mucinas
Limite:
Animals
Idioma:
En
Ano de publicação:
1997
Tipo de documento:
Article