Development of Self-Healing Cement Slurry through the Incorporation of Dual-Encapsulated Polyacrylamide for the Prevention of Water Ingress in Oil Well.

In the present work, a novel cross-linked polymer was synthesized though the anionic polymerization of cyanoacrylate with moisture as an initiator, methylene-bis-acrylamide as a cross-linker, and linseed oil as a spacer. Two layers of the synthesized polymer was coated over polyacrylamide for its homogenous impregnation in Class-G cement slurry for the synthesis of cement core. Fourier Transformation Infrared spectroscopy and X-Ray diffraction spectrum of the synthesized polymer and cement core were obtained to investigate the presence of different functional groups and phases. Moreover, the morphologies of the dual-encapsulated polyacrylamide was observed through scanning electron microscopy. Furthermore, the water-absorption capacity of the synthesized dual-encapsulated polyacrylamide in normal and saline conditions were tested. A cement core impregnated with 16% of dosage of dual-encapsulated polyacrylamide possesses an effective self-healing capability during the water-flow test. Moreover, the maximum linear expansion of the cement core was observed to be 26%. Thus, the impregnation of dual-encapsulated polyacrylamide in cement slurry can exhibit a superior self-healing behavior upon water absorption in an oil well.

An ultra-light flexible aerogel-based on methane derived CNTs as a reinforcing agent in silica-CMC matrix for efficient oil adsorption.

Bamboo shaped multi-walled Carbon Nanotubes were synthesized by the thermo-catalytic decomposition of methane in a modified chemical vapour deposition reactor. The prepared carbon nanotubes were reinforced in the mero-hydrophobic carboxymethyl cellulose and silica matrix for the preparation of low density, highly flexible aerogel. The synthesized aerogel exhibited a large specific surface area and uniform pore structure as confirmed by the nitrogen adsorption-desorption analysis. The water contact angle of 148.8° for the aerogel demonstrated that the synthesized aerogels were superhydrophobic in nature. The performance of aerogels was tested for the adsorption of singer oil and motor oil. Investigations revealed that aerogel can adsorb more than 28 times its weight effectively. Moreover, the adsorbed oil can be recovered by mechanical squeezing owing to its flexible nature. In addition, the aerogel could maintain its oil adsorption capacity even after 5 regeneration cycles, demonstrating superior recyclability. The peculiar properties - outstanding flexibility and superhydrophobicity exhibited by the aerogels establish them as a proficient and recyclable oil adsorbents during the oil seepage.