RESUMEN
Amorphous calcium carbonate is an important precursor for biomineralization in marine organisms. Key outstanding problems include understanding the structure of amorphous calcium carbonate and rationalizing its metastability as an amorphous phase. Here we report high-quality atomistic models of amorphous calcium carbonate generated using state-of-the-art interatomic potentials to help guide fits to X-ray total scattering data. Exploiting a recently developed inversion approach, we extract from these models the effective Caâ¯Ca interaction potential governing the structure. This potential contains minima at two competing distances, corresponding to the two different ways that carbonate ions bridge Ca2+-ion pairs. We reveal an unexpected mapping to the Lennard-Jones-Gauss model normally studied in the context of computational soft matter. The empirical model parameters for amorphous calcium carbonate take values known to promote structural complexity. We thus show that both the complex structure and its resilience to crystallization are actually encoded in the geometrically frustrated effective interactions between Ca2+ ions.
RESUMEN
In this work, coherent microwave scattering in the Thomson regime was demonstrated for small-scale plasmas enclosed within a glass tube and validated using a well-known hairpin resonator probe technique. The experiments were conducted in a DC discharge tube with a diameter of 1.5 cm and a length of 7 cm. Thomson microwave scattering (TMS) diagnostics yielded electron number densities of about 5.9 × 1010 cm-3, 2.8 × 1010 cm-3, and 1.8 × 1010 cm-3 for air pressures in the discharge tube of 0.2, 0.5, and 2.5 Torr, respectively. Measurements using the TMS technique were consistent across the tested microwave frequencies of 3-3.9 GHz within the margin of error associated with non-idealities of the IQ mixer utilized in the circuit. The corresponding densities measured with the hairpin resonator probe were 4.8 × 1010, 3.8 × 1010, and 2.6 × 1010 cm-3. Discrepancies between the two techniques were within 30% and can be attributed to inaccuracies in the sheath thickness estimation required for correct interpretation of the hairpin resonator probe results.
RESUMEN
The introduction of mid-IR optical parametric chirped pulse amplifiers has catalyzed interest in multimillijoule, infrared femtosecond pulse-based filamentation. As tunneling ionization is a fundamental first stage in these high-intensity laser-matter interactions, characterizing the process is critical to understand derivative topical studies on femtosecond filamentation and self-focusing. Here, we report direct nonintrusive measurements of total electron count and electron number densities generated at 3.9 µm femtosecond midinfrared tunneling ionization of atmospheric air using constructive-elastic microwave scattering. Subsequently, we determine photoionization rates to be in the range 5.0×10^{8}-6.1×10^{9}s^{-1} for radiation intensities of 1.3×10^{13}-1.9×10^{14}W/cm^{2}, respectively. The proposed approach paves the wave to precisely tabulate photoionization rates in mid-IR for a broad range of intensities and gas types and to study plasma dynamics at mid-IR filamentation.
RESUMEN
The total number of electrons in a classical microplasma can be non-intrusively measured through elastic in-phase coherent microwave scattering (CMS). Here, we establish a theoretical basis for the CMS diagnostic technique with an emphasis on Thomson and collisional scattering in short, thin unmagnetized plasma media. Experimental validation of the diagnostic is subsequently performed via linearly polarized, variable frequency (10.5-12 GHz) microwave scattering off laser induced 1-760 Torr air-based microplasmas (287.5 nm O2 resonant photoionization by ~ 5 ns, < 3 mJ pulses) with diverse ionization and collisional features. Namely, conducted studies include a verification of short-dipole-like radiation behavior, plasma volume imaging via ICCD photography, and measurements of relative phases, total scattering cross-sections, and total number of electrons [Formula: see text] in the generated plasma filaments following absolute calibration using a dielectric scattering sample. Findings of the paper suggest an ideality of CMS in the Thomson "free-electron" regime-where a detailed knowledge of plasma and collisional properties (which are often difficult to accurately characterize due to the potential influence of inhomogeneities, local temperatures and densities, present species, and so on) is unnecessary to extract [Formula: see text] from the scattered signal. The Thomson scattering regime of microwaves is further experimentally verified via measurements of the relative phase between the incident electric field and electron displacement.
RESUMEN
Median raphe cyst is a very rare, benign congenital lesion occurring mainly on the ventral aspect of the penis, but can develop anywhere in the midline between the external urethral meatus and anus. We report a case of median raphe cyst in the perineum presenting as a perianal polyp in a 65-year-old, English white male with exceptionally rare ciliated epithelium. According to our knowledge, this is the third such case of ciliated median raphe cyst in the English literature. This case, also the first case of ciliated median raphe cyst in the perineum location, focuses on pathogenesis of median raphe cyst.
