An excimer process induced a turn-on fluorescent probe for detection of ultra-low concentration of mercury ions.

The accumulation of mercury pollution in plants can induce severe injury to human beings. It is a great challenge to monitor ultra-low concentrations of mercury in complicated matrixes. In this study, we successfully developed a strategy via Hg2+-triggered naphthalene-based fluorescent probe 1, which formed excimer that subsequently emitted fluorescence for the successful detection of ultra-low concentrations of Hg2+. The coordination of N and S atoms with Hg2+ facilitated the formation of excimer from the naphthalene-conjugated planes that were in sufficiently close proximity. Suppression of CN bond rotation also induced the chelation-enhanced fluorescence (CHEF) effect, and the cumulative result of these effects was obvious fluorescent enhancement. Compared with probe 2, the other key factor for detection of Hg2+ is that the electrons of the hydroxyl group can easily transfer to a naphthalene moiety, resulting in an augmented π-electron density that enhanced the π-π stacking of the naphthalene-conjugated excimer. After detailed spectral studies and mechanism discussions, it was realized that probe 1 was able to detect ultra-low concentrations of Hg2+ in PBS buffer solution. The detection limit was calculated to be 1.98 nM. On account of the excellent performances, the probe was successfully applied in monitoring Hg2+ in water and pea sprouts with the potential for application as an advanced warning of contamination.

Nickel Single Atom Density-Dependent CO2 Efficient Electroreduction.

The transition metal-nitrogen-carbon (M─N─C) with MNx sites has shown great potential in CO2 electroreduction (CO2RR) for producing high value-added C1 products. However, a comprehensive and profound understanding of the intrinsic relationship between the density of metal single atoms and the CO2RR performance is still lacking. Herein, a series of Ni single-atom catalysts is deliberately designed and prepared, anchored on layered N-doped graphene-like carbon (x Ni1@NG-900, where x represents the Ni loading, 900 refers to the temperature). By modulating the precursor, the density of Ni single atoms (DNi) can be finely tuned from 0.01 to 1.19 atoms nm-2. The CO2RR results demonstrate that the CO faradaic efficiency (FECO) predominantly increases from 13.4% to 96.2% as the DNi increased from 0 to 0.068 atoms nm-2. Then the FECO showed a slow increase from 96.2% to 98.2% at -0.82 V versus reversible hydrogen electrode (RHE) when DNi increased from 0.068 to 1.19 atoms nm-2. The theoretical calculations are in good agreement with experimental results, indicating a trade-off relationship between DNi and CO2RR performance. These findings reveal the crucial role of the density of Ni single atoms in determining the CO2RR performance of M─N─C catalysts.

La@[La5&B30]0/-/2-: endohedral trihedral metallo-borospherenes with spherical aromaticity.

It is well-known that transition-metal-doping induces dramatic changes in the structures and bonding of small boron clusters, as demonstrated by the newly observed perfect inverse sandwich D8h [La(η8-B8)La] and D9h [La(η9-B9)La]-. Based on extensive global minimum searches and first-principles theory calculations, we predict herein the possibility of perfect endohedral trihedral metallo-borospherene D3h La@[La5&B30] (1, 3A'1) and its monoanion Cs La@[La5&B30]- (2, 2A') and dianion D3h La@[La5&B30]2- (3, 1A'1). These La-doped boron clusters are composed of three inverse sandwich La(η8-B8)La on the waist and two inverse sandwich La(η9-B9)La on the top and bottom which share one apex La atom at the center and six periphery B2 units between neighboring η8-B8 and η9-B9 rings, with three octo-coordinate La atoms and two nona-coordinate La atoms as integrated parts of the cage surface. Detailed adaptive natural density partitioning (AdNDP) and iso-chemical shielding surface (ICSS) analyses indicate that La@[La5&B30]0/-/2- (1/2/3) are spherically aromatic in nature. The one-dimensional nanowire La4B21 (4, P31m) constructed from D3h La@[La5&B30] (1) along the C3 axis of the system appears to be metallic. The IR and Raman spectra of La@[La5&B30] (1) and photoelectron spectroscopy of the slightly distorted Cs La@[La5&B30]- (2) are theoretically simulated to facilitate their spectroscopic characterizations.

Novel B-C binary fullerenes following the isolated B4C3 hexagonal pyramid rule.

B-C binary monolayers and fullerenes (borafullerenes) have received considerable attention in recent years. Inspired by the newly reported B4C3 semiconducting boron carbide monolayer isovalent to graphene (Tian et al., Nanoscale, 2019, 11, 11099), we predict herein at density functional theory level a new class of borafullerenes (1-8) following the isolated B4C3 hexagonal pyramid rule. The spherically aromatic borafullerenes C5h B20C35 (1), C5 B20C45 (2), C5h B20C55 (3), and C5 B20C65 (4) isovalent to C50, C60, C70, and C80, respectively, possess five isolated B4C3 hexagonal pyramids evenly distributed on the waist around the C5 molecular axis, while S10 B40C50 (5), C5 B40C60 (6), S10 B40C70 (7), and C5 B40C80 (8) encompass ten isolated B4C3 pyramids symmetrically distributed on the cage surface. Detailed orbital and bonding analyses indicate that these borafullerenes follow similar σ and π-bonding patterns with their fullerene analogues, with three delocalized 7c-2e π bonds forming a local π-aromatic system over each isolated B4C3 hexagonal pyramid. The calculated formation energies of the (B4C3)nC60-6n (n = 1-5) series isovalent to C60 appear to increase almost linearly with the number of isolated B4C3 pyramids in the system. The IR, Raman, and UV-vis spectra of the prototypical B20C45 (2) are theoretically simulated to facilitate its future spectral characterization.

Perfect cubic La-doped boron clusters La6&[La@B24]+/0 as the embryos of low-dimensional lanthanide boride nanomaterials.

La-doped boron nanoclusters have received considerable attention due to their unique structures and bonding. Inspired by recent experimental observations of the inverse sandwich D 8h La2B8 (1) and triple-decker C 2v La3B14 - (2) and based on extensive global searches and first-principles theory investigations, we present herein the possibility of the perfect cubic La-doped boron clusters O h La6&[La@B24]+ (3, 1A1g) and O h La6&[La@B24] (4, 2A2g) which appear to be the embryos of the metallic one-dimensional La10B32 (5) nanowire, two-dimensional La3B10 (6) nanosheet, and three-dimensional LaB6 (7) nanocrystal, facilitating a bottom-up approach to build cubic lanthanide boride nanostructures from gas-phase clusters. Detailed molecular orbital and bonding analyses indicate that effective (d-p)σ, (d-p)π and (d-p)δ covalent coordination interactions exist in La6&[La@B24]+/0 (3/4) clusters, while the 1D La10B32 (5), 2D La3B10 (6), and 3D LaB6 (7) crystals exhibit mainly electrostatic interactions between the trivalent La centers and cubic B24 frameworks, with weak but discernible coordination contributions from La (5d) ← B (2p) back-donations. The IR and Raman spectra of La6&[La@B24]+/0 (3/4) and band structures of La10B32 (5) and La3B10 (6) are computationally simulated to facilitate their future characterizations.

Low-dimensional functional networks of cage-like B40 with effective transition-metal intercalations.

As the first all-boron fullerene observed in experiments, cage-like borospherene B40 has attracted considerable attention in recent years. However, B40 has been proved to be chemically reactive and tends to coalesce with one another via the formation of covalent bonds. We explore herein the possibility of low-dimensional functional networks of B40 with effective transition-metal intercalations. We find that the four equivalent B7 heptagons on the waist of each B40 can serve as effective ligands to coordinate various transition metal centers in exohedral motifs. The intercalated metal atoms entail these networks with a variety of intriguing properties. The two-dimensional (2D) Cr2B40 network is a ferromagnetic metal while the 2D Zn2B40 network becomes semiconducting. In contrast, other 2D M2B40 (M = Sc, Ti, V, Mn, Fe, Co, Ni and Cu) networks and 1D CrB40 belong to nonmagnetic metals. The 3D Cr3B40 network is a magnetic metal. This work presents the viable possibility of assembling Mn&B40 metalloborospherenes into stable functional nanomaterials via effective transition-metal intercalations with potential applications in electronic and spintronic devices.

High-symmetry tubular Ta@B183-, Ta2@B18, and Ta2@B27+ as embryos of α-boronanotubes with a transition-metal wire coordinated inside.

Transition-metal doping leads to dramatic structural changes and results in novel bonding patterns in small boron clusters. Based on the experimentally derived mono-ring planar C9v Ta©B92- (1) and extensive first-principles theory calculations, we present herein the possibility of high-symmetry double-ring tubular D9d Ta@B183- (2) and C9v Ta2@B18 (3) and triple-ring tubular D9h Ta2@B27+ (4), which may serve as embryos of single-walled metalloboronanotube α-Ta3@B48(3,0) (5) wrapped up from the recently observed most stable free-standing boron α-sheet on a Ag(111) substrate with a transition-metal wire (-Ta-Ta-) coordinated inside. Detailed bonding analyses indicate that, with an effective dz2-dz2 overlap on the Ta-Ta dimer along the C9 molecular axis, both Ta2@B18 (3) and Ta2@B27+ (4) follow the universal bonding pattern of σ + π double delocalization with each Ta center conforming to the 18-electron rule, providing tubular aromaticity to these Ta-doped boron complexes with magnetically induced ring currents. The IR, Raman, and UV-vis spectra of 3 and 4 are computationally simulated to facilitate their future experimental characterization.

Cage-like Ta@B complexes (n = 23-28, q = -1-+ 3) in 18-electron configurations with the highest coordination number of twenty-eight.

Inspired by recent observations of the highest coordination numbers of CN = 10 in planar wheel-type complexes in D10h Ta@B10- and CN = 20 in double-ring tubular species in D10d Ta@B20- and theoretical prediction of the smallest endohedral metalloborospherene D2 Ta@B22- (1) with CN = 22, we present herein the possibility of larger endohedral metalloborospherenes C2 Ta@B23 (2), C2 Ta@B24+ (3), C2v Ta@B24- (4), C1 Ta@B25 (5), D2d Ta@B26+ (6), C2 Ta@B272+ (7), and C2 Ta@B283+ (8) based on extensive first-principles theory investigations. These cage-like Ta@Bqn complexes with B6 pentagonal or B7 hexagonal pyramids on their surface turn out to be the global minima of the systems with CN = 23, 24, 24, 25, 26, 27, and 28, respectively, unveiling the highest coordination number of CN = 28 in spherical environments known in chemistry. Detailed bonding analyses show that 1-8 as superatoms conform to the 18-electron configuration with a universal σ + π double delocalization bonding pattern. They are effectively stabilized via spd-π coordination interactions between the Ta center and ηn-Bn ligand which match both geometrically and electronically. Such complexes may serve as embryos of novel metal-boride nanomaterials.

Structural transition in metal-centered boron clusters: from tubular molecular rotors Ta@B21 and Ta@B22+ to cage-like endohedral metalloborospherene Ta@B22.

Inspired by the recent discovery of the metal-centered tubular molecular rotor Cs B2-Ta@B18- with the record coordination number of CN = 20 and based on extensive first-principles theory calculations, we present herein the possibility of the largest tubular molecular rotors Cs B3-Ta@B18 (1) and C3v B4-Ta@B18+ (2) and smallest axially chiral endohedral metalloborospherenes D2 Ta@B22- (3 and 3'), unveiling a tubular-to-cage-like structural transition in metal-centered boron clusters at Ta@B22-via effective spherical coordination interactions. The highly stable Ta@B22- (3) as an elegant superatom, which features two equivalent corner-sharing B10 boron double chains interconnected by two B2 units with four equivalent B7 heptagons evenly distributed on the cage surface, conforms to the 18-electron configuration with a bonding pattern of σ + π double delocalization and follows the 2(n + 1)2 electron counting rule for spherical aromaticity (n = 2). Its calculated adiabatic detachment energy of ADE = 3.88 eV represents the electron affinity of the cage-like neutral D2 Ta@B22 which can be viewed as a superhalogen. The infrared, Raman, VCD, and UV-vis spectra of the concerned species are computationally simulated to facilitate their spectral characterizations.