Subthreshold slope below 60 mV/decade in graphene transistors induced by channel geometry at the wafer-scale.

In this paper, we demonstrate experimentally that field-effect transistors with nanoconstricted graphene monolayer channels have a subthreshold swing (SS) below 60 mV/dec, which is slightly dependent on temperature. Two shapes of nanoconstricted graphene monolayers are considered: (i) a bow-tie shape, representative for a symmetric channel, and (ii) a trapezoidal shape, which illustrates an asymmetric channel. While both types of nonuniform channels are opening a bandgap in graphene, thus showing an on/off ratio of 105, the SS in the graphene bow-tie channel is below 60 mV/dec in the temperature range 25 °C-44 °C.

Quantum Graphene Asymmetric Devices for Harvesting Electromagnetic Energy.

We present here the fabrication at the wafer level and the electrical performance of two types of graphene diodes: ballistic trapezoidal-shaped graphene diodes and lateral tunneling graphene diodes. In the case of the ballistic trapezoidal-shaped graphene diode, we observe a large DC current of 200 µA at a DC bias voltage of ±2 V and a large voltage responsivity of 2000 v/w, while in the case of the lateral tunneling graphene diodes, we obtain a DC current of 1.5 mA at a DC bias voltage of ±2 V, with a voltage responsivity of 3000 v/w. An extended analysis of the defects produced during the fabrication process and their influences on the graphene diode performance is also presented.

Synthesis and characterization of polyurethane flexible foams provided from PET derivatives, fly ash, and glass wastes.

The aim of this study involved the synthesis and characterization of polyurethane (PUR) foams obtained from poly(ethylene terephthalate) (PET) depolymerization products and two types of filling agents, namely fly ash and glass waste. The depolymerized PET-based products were obtained by zinc acetate-catalyzed glycolysis process in diethylene glycol (DEG) as a co-reactant. The resulting glycolysis products were contacted with methylene diphenyl diisocyanate, castor oil, and reinforcing agents. The resulting PUR specimens were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), EDX mapping, mechanical tests, and thermal analysis. The analysis confirmed that the best mechanical performances were registered by the specimens with the lowest concentration of filling agent, while the highest thermal resistance was achieved by the PUR foams with the highest concentration of reinforcing agent.