RESUMO
Efficient room temperature NIR detection with sufficient current gain is made with a solution-processed networked SWNT FET. The high performance NIR-FET with significantly enhanced photocurrent by more than two orders of magnitude compared to dark current in the depleted state is attributed to multiple Schottky barriers in the network, each of which absorb NIR and effectively separate photocarriers to corresponding electrodes.
RESUMO
BACKGROUND: Belt or wire shaped TiO2(B) particles were synthesized for lithium ion battery application by a hydrothermal and heat treatment process. In order to facilitate TiO2(B)/C composites fabrication, the synthesized TiO2(B) particles were crushed into smaller sizes by ball milling. RESULTS: Ball mill treated TiO2(B) particles of less than 1.0 µm with a fraction of anatase phase, compared to as-synthesized TiO2(B) particles with about 24 µm in average particle size, showed a significant improvement in the electrochemical properties. They showed a much improved stability in the charge-discharge cycles and irreversibility. They maintained about 98% of the initial capacity during 50 cycles while as-synthesized sample before ball mill treatment showed a gradual decrease in the capacity with the cycles. The irreversibility of 12.4% of as-synthesized sample was also greatly improved to 7% after ball milling treatment. CONCLUSIONS: Our results indicate ball mill treatment can be an economical way to improve electrochemical properties of TiO2(B) anode materials for lithium ion battery application.