A Comparative Study of Cellulose Ethers as Thermotropic Materials for Self-Tracking Solar Concentrators.

The continuous growth in energy demand requires researchers to find new solutions to enlarge and diversify the possible ways of exploiting renewable energy sources. Our idea is the development of a solar concentrator based on trapping the luminous radiation with a smart window. This system is able to direct light towards the photovoltaic cells placed on window borders and produce electricity, without any movable part and without changing its transparency. Herein, we report a detailed study of cellulose ethers, a class of materials of natural origin capable of changing their state, from transparent aqueous solution to scattering hydrogel, in response to a temperature change. Cellulose thermotropism can be used to produce a scattering spot in a window filled with the thermotropic fluid to create a new kind of self-tracking solar concentrator. We demonstrate that the properties of the thermotropic fluid can be finely tuned by selecting the cellulose functionalization, the co-dissolved salt, and by regulating their dosage. Lastly, the results of our investigation are tested in a proof-of-concept demonstration of solar concentration achieved by thermotropism-based light trapping.

Integration of Phase Change Material in the Design of Solar Concentrator-Based Water Heating System.

Indonesia has been blessed with excellent solar heat distribution, which can be used as renewable energy to heat water. Various technologies have been developed to utilize these inexhaustible thermodynamic resources, in the form of photons arrays, converted into concentrated heat for daily use, i.e., solar water heater. This renewable-based water heating system can provide significant energy efficiency, benefit the environment, and reduce energy use costs. This experimental study attempts to harvest the energy from the sun using a cylindrical through collector (CTC) type solar concentrator. The CTC was made of the solar reflective film (SRF) affixed to concentrator collector surfaces which was then mounted on an adjustable angle frame of the concentrator collector support. The heat generated from the concentrator was stored in water, and phase change material is embedded in the system to retain the heat longer. The research was carried out in Langsa City, Aceh, Indonesia. The results showed that water heaters using CTC systems could produce 16 L of hot water retained at 40-60 °C for four hours. With the addition of beeswax, the water temperature of the same capacity can be maintained at 40-60 °C for around 5 h. This technology demonstrated an excellent result that produces as much as 60 L of water per day, increasing solar thermal energy efficiency. This technology presented a great potential for replication or even for further development on an industrial scale.

Realization of a solar hydrothermal carbonization reactor: A zero-energy technology for waste biomass valorization.

Research around hydrothermal carbonization (HTC) has seen a huge development in recent years, materializing in the first pilot and industrial plants. Even though HTC reactions are slightly exothermic, the overall process entails energy consumption to both reach operating conditions and tackle heat losses. To face this issue and to develop a zero-energy process, this work proposes an innovative solution: the coupling of an HTC reactor with a solar concentrator, designed to fully cover the HTC energy needs. A 300 ml stainless steel HTC reactor was constructed and positioned on the focus of a parabolic dish concentrator (PDC), consisting of one parabolic mirror of 0.8 m2. To maximize the light absorption, the illuminated side of the HTC reactor was coated with a thin layer of nanostructured copper oxide, realized via electron beam deposition. Then, the effectiveness of the hybrid solar-HTC solution was demonstrated by carrying out an experimental campaign on a residual agro-biomass (grape seeds), which was treated at 180, 220, and 250 °C for 2 h. The coating confers excellent absorbing performances to the system, exhibiting an absorptance of up to 95.6% (at 300 nm wavelength). Heating times, yields, composition, and energy properties of "solar hydrochars" resemble those of studies performed in traditional HTC systems. This research work proves the feasibility of the solar-HTC prototype apparatus and opens the way to the development of a zero-energy solar-HTC technology.

Performance Limits of Luminescent Solar Concentrators Tested with Seed/Quantum-Well Quantum Dots in a Selective-Reflector-Based Optical Cavity.

Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors for photovoltaic devices. An important LSC characteristic is a concentration factor (C), which is defined as the ratio of the output and the input photon flux densities. This parameter can be also thought of as an effective enlargement factor of a solar cell active area. On the basis of thermodynamic considerations, the C-factor can reach extremely high values that exceed those accessible with traditional concentrating optics. In reality, however, the best reported values of C are around 30. Here we demonstrate that using a new type of high-emissivity quantum dots (QDs) incorporated into a specially designed cavity, we are able to achieve the C of ∼62 for spectrally integrated emission and ∼120 for the red portion of the photoluminescence spectrum. The key feature of these QDs is a seed/quantum-well/thick-shell design, which allows for obtaining a high emission quantum yield (>95%) simultaneously with a large LSC quality factor (QLSC of ∼100) defined as the ratio of absorption coefficients at the wavelengths of incident and reemitted light. By incorporating the QDs into a specially designed cavity equipped with a top selective reflector (a Bragg mirror or a thin silver film), we are able to effectively recycle reemitted light achieving light trapping coefficients of ∼85%. The observed performance of these devices is in remarkable agreement with analytical modeling, which allows us to project that the applied approach should allow one to boost the spectrally integrated concentration factors to more than 100 by further improving light trapping and/or increasing QLSC.

A Leaf-Inspired Luminescent Solar Concentrator for Energy-Efficient Continuous-Flow Photochemistry.

The use of solar light to promote chemical reactions holds significant potential with regard to sustainable energy solutions. While the number of visible light-induced transformations has increased significantly, the use of abundant solar light has been extremely limited. We report a leaf-inspired photomicroreactor that constitutes a merger between luminescent solar concentrators (LSCs) and flow photochemistry to enable green and efficient reactions powered by solar irradiation. This device based on fluorescent dye-doped polydimethylsiloxane collects sunlight, focuses the energy to a narrow wavelength region, and then transports that energy to embedded microchannels where the flowing reactants are converted.

Nanocrystals for luminescent solar concentrators.

Luminescent solar concentrators (LSCs) harvest sunlight over large areas and concentrate this energy onto photovoltaics or for other uses by transporting photons through macroscopic waveguides. Although attractive for lowering solar energy costs, LSCs remain severely limited by luminophore reabsorption losses. Here, we report a quantitative comparison of four types of nanocrystal (NC) phosphors recently proposed to minimize reabsorption in large-scale LSCs: two nanocrystal heterostructures and two doped nanocrystals. Experimental and numerical analyses both show that even the small core absorption of the leading NC heterostructures causes major reabsorption losses at relatively short transport lengths. Doped NCs outperform the heterostructures substantially in this critical property. A new LSC phosphor is introduced, nanocrystalline Cd(1-x)Cu(x)Se, that outperforms all other leading NCs by a significant margin in both small- and large-scale LSCs under full-spectrum conditions.

Design and realization of transparent solar modules based on luminescent solar concentrators integrating nanostructured photonic crystals.

Herein, we present a prototype of a photovoltaic module that combines a luminescent solar concentrator integrating one-dimensional photonic crystals and in-plane CuInGaSe2 (CIGS) solar cells. Highly uniform and wide-area nanostructured multilayers with photonic crystal properties were deposited by a cost-efficient and scalable liquid processing amenable to large-scale fabrication. Their role is to both maximize light absorption in the targeted spectral range, determined by the fluorophore employed, and minimize losses caused by emission at angles within the escape cone of the planar concentrator. From a structural perspective, the porous nature of the layers facilitates the integration with the thermoplastic polymers typically used to encapsulate and seal these modules. Judicious design of the module geometry, as well as of the optical properties of the dielectric mirrors employed, allows optimizing light guiding and hence photovoltaic performance while preserving a great deal of transparency. Optimized in-plane designs like the one herein proposed are of relevance for building integrated photovoltaics, as ease of fabrication, long-term stability and improved performance are simultaneously achieved. © 2015 The Authors. Progress in Photovoltaics: Research and Applications published by John Wiley & Sons Ltd.

Harnessing the Synergetic Effects of Ag, Mn Dopants in Eco-Friendly Ultraviolet Selective Quantum Dots for Luminescent Solar Concentrators.

Quantum dots (QDs) are promising building blocks for luminescent solar concentrators (LSCs), yet most QD-based LSCs suffer from toxic metal composition and color tinting. UV-selective harvesting QDs can enable visible transparency, but their development is restricted by large reabsorption losses and low photoluminescence quantum yield (PLQY). The developed here Ag, Mn: ZnInS2/ZnS QDs show a high PLQY of 53% due to the passivating effect of ZnS shell. These QDs selectively absorb UV light and emit orange-red light with a large Stokes shift of 180 nm. A LSC of 5 × 5 × 0.2 cm3, fabricated using a poly(lauryl methacrylate) (PLMA) as a matrix, maintains 87% of integrated PL after 7 h of UV exposure. The QD-PLMA achieved 90.7% average visible transparency (AVT) and a color rendering index (CRI) of 95.8, which is close to plain PLMA (AVT = 90.8%; CRI = 99.5), yielding excellent visible light transparency. Incorporating Si-PVs at LSC edges, the Ag, Mn: ZIS/ZnS QD-LSC achieved an optical efficiency of 1.42%, ranking competitively among high-performing UV-harvesting LSCs.

Sensitivity analysis of the thermal performance of a parabolic trough concentrator using Al2O3 and SiO2/Vegetable oil as heat transfer fluid.

This paper aims to highlight the use of different heat transfer fluid (HTF) configurations based on vegetable oils in Parabolic Trough Solar Concentrator (PTSC). Rapeseed and jatropha oils as innovative heat transfer materials combined with SiO2 and Al2O3 to obtain six (6) HTF configurations are used in a 1-dimensional PTSC model. The thermophysical properties of the nanofluids are determined from correlations derived from the literature, using Gauss-Seidel method from a numerical code developed in Matlab software. Model validation is obtained. Thermal sensitivity analysis shows that the use of rapeseed increases the thermal efficiency of the PTSC by around 4.21 % compared with jatropha. The use of nanofluids reduces thermal losses within the system due to thermal gradients. For a fixed irradiance and each 1 %-4 % increase in volume fraction, thermal efficiency increases by around 1.96 % when Al2O3/rapeseed is used and by 0.47 % when SiO2/rapeseed is used compared with rapeseed. Similarly, thermal efficiency increases by around 1.98 % when Al2O3/jatropha is used and decreases by around 0.20 % when SiO2/jatropha is used compared with jatropha. However, the positive effects of nanoparticles on thermal conductivity alone are not always sufficient to improve thermal efficiency, and thermal effects on heat capacity should also be considered.

Intense Near-Infrared Light-Emitting NaYF4:Nd,Yb-Based Nanophosphors for Luminescent Solar Concentrators.

In this study, we synthesized NaYF4-based downshifting nanophosphors (DSNPs), and fabricated DSNP-polydimethylsiloxane (PDMS) composites. Nd3+ ions were doped into the core and shell to increase absorbance at 800 nm. Yb3+ ions were co-doped into the core to achieve intense near-infrared (NIR) luminescence. To further enhance the NIR luminescence, NaYF4:Nd,Yb/NaYF4:Nd/NaYF4 core/shell/shell (C/S/S) DSNPs were synthesized. The C/S/S DSNPs showed a 3.0-fold enhanced NIR emission at 978 nm compared with core DSNPs under 800 nm NIR light. The synthesized C/S/S DSNPs showed high thermal stability and photostability against the irradiation with ultraviolet light and NIR light. Moreover, for application as luminescent solar concentrators (LSCs), C/S/S DSNPs were incorporated into the PDMS polymer, and the DSNP-PDMS composite containing 0.25 wt% of C/S/S DSNP was fabricated. The DSNP-PDMS composite showed high transparency (average transmittance = 79.4% for the visible spectral range of 380-750 nm). This result demonstrates the applicability of the DSNP-PDMS composite in transparent photovoltaic modules.

Performance study on a solar concentrator system for water distillation using different water nanofluids.

The rapid growth in the world-population urges the need for potable water in various regions, especially in hot and dry regions. The main challenge in the productivity of potable water is the cost and availability of water sources. Thus, it is crucial to develop effective methods to overcome this global need. Utilizing solar power is proven to be a promising path to implementing thermal solar radiation in solar distillation applications. This work investigates the effectiveness of using concentrated solar power to irradiate heat exchange to evaporate water in a receiver, which will be collected as pure water in a condenser later. The thermal performance of the proposed model and its productivity are tested experimentally by using tap water only, and the test was repeated twice using two nanofluids namely, (aluminium oxide (Al2O3) and zinc oxide (ZnO)). The results showed that using (Al2O3) has a superior influence on the productivity of the solar unit, where the productivity is increased by 43.53% and 21.89% when compared to tap water and zinc oxide (ZnO) nanofluid respectively. The thermal efficiency of the solar unit was also increased by 9.91% (maximum) when using (aluminium oxide (Al2O3) as a working fluid compared to tap water. The model has simple components and is easy to install with a compact size, which can be developed be utilized in urban and desert areas.

Effect of Polymer Composition on the Optical Properties of a New Aggregation-Induced Emission Fluorophore: A Combined Experimental and Computational Approach.

Nowadays, fluorophores with a tetraphenylethylene (TPE) core are considered interesting due to the aggregation-induced emission (AIE) behavior that enables their effective use in polymer films. We propose a novel TPE fluorophore (TPE-BPAN) bearing two dimethylamino push and a 4-biphenylacetonitrile pull moieties with the typical AIE characteristics in solution and in the solid state, as rationalized by DFT calculations. Five different host polymer matrices with different polarity have been selected: two homopolymers of poly(methylmethacrylate) (PMMA) and poly(cyclohexyl methacrylate) (PCHMA) and three copolymers at different compositions (P(MMA-co-CHMA) 75:25, 50:50, and 25:75 mol%). The less polar comonomer of CHMA appeared to enhance TPE-BPAN emission with the highest quantum yield (QY) of about 40% measured in P(MMA-co-CHMA) 75:25. Further reduction in polymer polarity lowered QY and decreased the film stability and adhesion to the glass surface. LSC performances were not significantly affected by the matrix's polarity and resulted in around one-third of the state-of-the-art due to the reduced QY of TPE-BPAN. The theoretical investigation based on density functional theory (DFT) calculations clarified the origin of the observed AIE and the role played by the environment in modulating the photophysical behavior.

Performance of Luminescent Solar Concentrators Integrated with Negative Replica Layers of Leaf Surface Microstructures.

In this study, a negative replica layer of leaf surface microstructures was used to cover the top surfaces of semitransparent thin-film luminescent solar concentrators (LSCs) to enhance the concentrators' performance. With low reflection on the air-glass interface of the glass plate in a thin-film LSC, a negative replica layer enables the scattering of incident sunlight and increases the path of light transmitted into the LSC and the thin phosphor layer at the bottom surface of the LSC. The incident sunlight is therefore more likely to interact with the phosphor particles in the thin-film phosphor layer, thereby enhancing the performance of the LSC. In this study, semitransparent thin-film LSCs with different inorganic phosphors were examined. The experimental results revealed that the optical collection efficiency of semitransparent thin-film LSCs covered with negative replica layers of leaf surface microstructures was higher than that of the semitransparent thin-film LSCs without negative replica layers. Furthermore, the LSCs with negative replica layers with high haze ratios exhibited high optical collection efficiency. Integrating negative replica layers of leaf surface microstructures as semitransparent layers in thin-film LSCs may optimize the application of LSCs in building-integrated photovoltaics (BIPVs).

Highly Luminescent and Stable Organic-Inorganic Hybrid Films for Transparent Luminescent Solar Concentrators.

Here, a highly luminescent, stable, and visible-transparent organic-inorganic hybrid film was in situ synthesized in a siloxane-polyether (di-ureasil) sol-gel process by dissolving a 4-hydroxy-2-methyl-1,5-naphthyridine-3-carbonitrile (2mCND) ligand and a europium(III) ion. Doping a europium(III) complex into di-ureasil achieves an boost in photoluminescence quantum efficiency (PLQY) from 23.25 to 68.9%. In particular, the excellent photostability of the hybrid film was demonstrated after a 15 h aging experiment in strong UV-LED irradiation (∼468 mW/cm2). Compared to the polymethyl methacrylate (PMMA) matrix, di-ureasil containing a europium(III) complex shows an improved UV resistance, making it a promising candidate for various photonic applications. By integrating the hybrid film onto an acrylic substrate, a transparent luminescent solar concentrator (LSC) was fabricated, which reveals an optical conversion efficiency of ∼0.51% with a G factor of 3.1 at an optical transmission level of ∼90%. Such an LSC could be of particular interest in future transparent photovoltaic windows.

Effects of Nanoscale Morphology on Optical Properties of Photoluminescent Polymer Optical Fibers.

Bicomponent photoluminescent polymer optical fibers (PL-POFs) have been melt-spun and in-situ drawn to different extents. The results suggest that scattering in the sheath can effectively increase the photoluminescent dye excitation probability in the fiber core. The core/sheath PL-POFs are made of a semi-crystalline fluoropolymer sheath of low refractive index (RI) and an amorphous cycloolefin polymeric core of high RI, which is doped with a luminescent dye. The axial light emission, as well as the guiding attenuation coefficients of the core/sheath PL-POFs, have been measured using a side-illumination set-up. The incident blue laser is down-converted to red light, which is re-emitted and partially guided by the core. The axial light emission is measured at the fiber tip as a function of the distance from the illumination position to the integrating sphere. It is demonstrated that the presence of a semi-crystalline sheath significantly enhances the axial light emission and that it also lowers the attenuation coefficient, compared to the emission and guiding properties of PL core-only fibers. Additionally, the attenuation coefficient has been found to be lower in more strongly drawn PL-POFs. Wide-angle X-ray diffraction and small-angle X-ray scattering experiments reveal structural differences in differently drawn PL-POFs that can be linked to the observed differences in the optical properties.

Förster Resonance Energy Transfer in Luminescent Solar Concentrators.

Luminescent solar concentrators (LSCs) are an emerging technology to collect and channel light from a large absorption area into a smaller one. They are a complementary technology for traditional solar photovoltaics (PV), particularly suitable for application in urban or indoor environments where their custom colors and form factors, and performance under diffuse light conditions may be advantageous. Förster resonance energy transfer (FRET) has emerged as a valuable approach to overcome some of the intrinsic limitations of conventional single lumophore LSCs, such as reabsorption or reduced quantum efficiency. This review outlines the potential of FRET to boost LSC performance, using highlights from the literature to illustrate the key criteria that must be considered when designing an FRET-LSC, including both the photophysical requirements of the FRET lumophores and their interaction with the host material. Based on these criteria, a list of design guidelines intended to aid researchers when they approach the design of a new FRET-LSC system is presented. By highlighting the unanswered questions in this field, the authors aim to demonstrate the potential of FRET-LSCs for both conventional solar-harvesting and emerging LSC-inspired technologies and hope to encourage participation from a diverse researcher base to address this exciting challenge.

Minimizing Scaling Losses in High-Performance Quantum Dot Luminescent Solar Concentrators for Large-Area Solar Windows.

While luminescent solar concentrators (LSCs) have been researched for several decades, there is still a lack of commercially available systems, mostly due to scalability, performance, aesthetics, or some combination of these challenges. These obstacles can be overcome by the systematic optimization of a laminated glass LSC design, demonstrated herein. In particular, we first show that it is possible to improve optical and electrical efficiencies of an LSC by fine-tuned optimization of the constituent fluorophore-containing interlayer resin. Further still, an increased understanding of commercially available solar cells allows us to establish a direct correlation between the device's optical and electrical efficiency. Next, optical characterization of LSCs of varying sizes allows us to elucidate the main loss mechanisms in our LSCs, as well as ways to mitigate them. Altogether these optimization steps create opportunities for high-performance multi-interlayer LSC devices with demonstrated electrical power conversion efficiency as high as 1.1% to 4.9% at visual light transmission of 74% to 5%. Furthermore, careful examination of different blue-color (red-band absorbing) dyes provides a path for color-tunability of LSC windows toward neutral regimes. Design iterations of multiple device form factors enabled a color-neutral prototype without significant performance losses by separating color-neutralizing and LSC layers into different panes of an insulated glass unit. This work demonstrates the importance of LSC design optimization in achieving high-performance solar window technology with commercially acceptable aesthetics.

Bio-Based Solar Energy Harvesting for Onsite Mobile Optical Temperature Sensing in Smart Cities.

The Internet of Things (IoT) fosters the development of smart city systems for sustainable living and increases comfort for people. One of the current challenges for sustainable buildings is the optimization of energy management. Temperature monitoring in buildings is of prime importance, as heating account for a great part of the total energy consumption. Here, a solar optical temperature sensor is presented with a thermal sensitivity of up to 1.23% °C-1 based on sustainable aqueous solutions of enhanced green fluorescent protein and C-phycocyanin from biological feedstocks. These photonic sensors are presented under the configuration of luminescent solar concentrators widely proposed as a solution to integrate energy-generating devices in buildings, as windows or façades. The developed mobile sensor is inserted in IoT context through the development of a self-powered system able to measure, record, and send data to a user-friendly website.

Solar parabolic dish collector for concentrated solar thermal systems: a review and recommendations.

Energy demand in the present scenario is rising to meet the increasing demands of energy usage. On the other hand, the use for renewable energy sources now becomes essential to mitigate the climate change as well as to reduce gradual depletion of fossil fuels. Among these renewable energy sources, solar energy particularly solar thermal systems have phenomenal scope in present and future research. In solar thermal systems, concentrators are used to extract the energy from solar irradiation and convert it into useful form. Among different types of solar concentrators, the parabolic dish solar concentrator is preferred as it has high efficiency, high power density, low maintenance, and potential for long durability. In this paper, a detailed review has been carried out on the design parameters like focal length, concentration ratio, and rim angle of the parabolic dish solar concentrator system for achieving higher overall efficiency. The effects of different geometrical shapes of receivers on the overall heat transfer rates are discussed in this paper. Conical shaped receiver is having high overall optical and thermal efficiency comparing with other shapes of receivers. This study also shows that how the thermal performance of the receiver gets enhanced by 10-13% using nanofluids in place of general heat transfer fluids. The paper highlights different models using ray-tracing method for estimation and evaluation of the solar irradiation distribution on the receiver surface. The empirical relations for the design of parabolic dish solar concentrator system are derived for estimating overall concentrator efficiency and heat available at the receiver are given in this review. From the literature, the thermal performance of the receiver affecting the overall performance of the system is observed. Thermal losses due to geometrical properties and ordination of the receiver are explained in the observation section.

Thermal-Optical Evaluation of an Optimized Trough Solar Concentrator for an Advanced Solar-Tracking Application Using Shape Memory Alloy.

One of the modern methods for enhancing the efficiency of photovoltaic (PV) systems is implementing a solar tracking mechanism in order to redirect PV modules toward the sun throughout the day. However, the use of solar trackers increases the system's electrical consumption, hindering its net generated energy. In this study, a novel self-tracking solar-driven PV system is proposed. The smart solar-driven thermomechanical actuator takes advantage of a solar heat collector (SHC) device, in the form of a parabolic trough solar concentrator (PTC), and smart shape memory alloy (SMA) to produce effective mechanical energy for solar tracking applications from sun rays. Furthermore, a thermal-optical analysis is presented to evaluate the performance of the solar concentrator for the simulated weather condition of Dammam City, Saudi Arabia. The numerical results of the thermal and optical analyses show the promising feasibility of the proposed system in which SMA springs with an activation temperature between 31.09 °C and 45.15 °C can be utilized for the self-tracking operations. The work presented adds to the body of knowledge an advanced SMA-based SHC device for solar-based self-actuation systems, which enables further expansions within modern and advanced solar thermal applications.