Tetracene film morphology: comparative atomic force microscopy, X-ray diffraction and ellipsometry investigations.

X-ray diffraction, atomic force microscopy and spectroscopic ellipsometry were used to study tetracene thin films as a function of deposition rate. A comparative analysis of the thickness and roughness values allows for detailed modelling of the film morphology. An interdigitated growth mode is established for the coexisting thin film and bulk phases. By comparison with the respective quinone-derivative of tetracene, we were additionally able to identify reaction products by their optical response.

Kramers-Kronig-consistent optical functions of anisotropic crystals: generalized spectroscopic ellipsometry on pentacene.

The Kramers-Kronig relations between the real and imaginary parts of a response function are widely used in solid-state physics to evaluate the corresponding quantity if only one component is measured. They are among the most fundamental statements since only based on the analytical behavior and causal nature of the material response [Phys. Rev. 104, 1760-1770 (1956)]. Optical losses, for instance, can be obtained from the dispersion of the dielectric constant at all wavelengths, and vice versa [Handbook of optical constants of solids, Vol. 1, p. 35]. Although the general validity was never casted into doubt, it is a longstanding problem that Kramers-Kronig relations cannot simply be applied to anisotropic crystalline materials because contributions from different directions mix in a frequency-dependent way. Here we present a general method to identify frequency-independent principal polarizability directions for which the Kramers-Kronig relations are obeyed even in materials with lowest symmetry. Using generalized spectroscopic ellipsometry on a single crystal surface of triclinic pentacene, as an example, enables us to evaluate the complex dielectric constant and to compare it with band-structure calculations along the crystallographic directions. A general recipe is provided how to proceed from a macroscopic measurement on a low symmetry crystal plane to the microscopic dielectric properties of the unit cell, along whose axes the Kramers-Kronig relations hold.

Nanometer-thick Au-films as antireflection coating for infrared light.

The optical properties of ultrathin Au films on silicon have been studied in the infrared over a wide frequency range from 200 to 10,000 cm(-1). Thick films show a Drude behavior; i.e., with increasing frequency the transmission increases; for films below the percolation threshold at about 5 nm a negative slope for the frequency-dependent transmission is observed. When the thickness is further reduced, between 1 and 3 nm an anomaly occurs: the relative transmission reaches maximum values above 100% compared with the bare substrate, indicating an antireflection coating of nanometer thickness for light of 5 microm wavelength. This anomaly can be explained in the framework of effective-medium theories.

Microspectroscopy and imaging in the THz range using coherent CW radiation.

A novel THz near-field spectrometer is presented which allows the performance of biological and medical studies with high spectral resolution combined with a spatial resolution down to lambda/100. In the setup an aperture much smaller than the used wavelength is placed in the beam very close to the sample. The sample is probed by the evanescent wave behind the aperture. The distance is measured extremely accurately by a confocal microscope. We use monochromatic sources which provide powerful coherent cw radiation tuneable from 50 GHz up to 1.5 THz. Transmission and reflection experiments can be performed which enable us to study solids and molecules in aqueous solution. Examples for spectroscopic investigations on biological tissues are presented.

Does water vapor prevent upscaling sonoluminescence?

Experimental results for single-bubble sonoluminescence of air bubbles at very low frequency f = 7.1 kHz are presented: In contrast to the predictions of a recent model [S. Hilgenfeldt and D. Lohse, Phys. Rev. Lett. 82, 1036 (1999)], the bubbles are only as bright (10(4)-10(5) photons per pulse) and the pulses as long (approximately 150 ps) as at f = 20 kHz. We can theoretically account for this effect by incorporating water vapor into the model: During the rapid bubble collapse a large amount of water vapor is trapped inside the bubble, resulting in an increased heat capacity and hence lower temperatures, i.e., hindering upscaling. At this low frequency water vapor also dominates the light emission process.

Microimplosions: cavitation collapse and shock wave emission on a nanosecond time scale

A streak camera with high spatial and temporal resolution was used for imaging the dynamics of the violent collapse in single-bubble sonoluminescence. The high pressure in the last phase of the bubble collapse leads to the emission of a shock wave, which is launched with a shock velocity of almost 4000 m/s. The shock amplitude decays much faster than approximately 1/r. From the strongly nonlinear propagation the pressure in the vicinity of the bubble can be calculated to be in the range of 40-60 kbar.

Mie scattering from a sonoluminescing bubble with high spatial and temporal resolution

The dynamics of a single-air bubble trapped in a resonant sound field in water has been characterized by Mie scattering and a Streak camera with high spatial and temporal resolution. The streak images show that in the endphase of the cavitation collapse the scattered light intensity is no function of the bubble radius anymore. In the last nanoseconds around minimum bubble radius most of the light is scattered at the highly compressed water surrounding the bubble and not at the bubble wall. This leads to a minimum in the scattered light intensity about 700 ps before the sonoluminescence pulse is emitted. And neglecting this changes leads to a strong overestimation of the bubble-wall velocity. In the reexpansion phase the high spatial resolution of the streak camera allows one to distinguish between the light scattered at the bubble wall and the light scattered at the outgoing shock wave.

Quantification of postural sway in normals and patients with cerebellar diseases.

Posturography was performed in 41 patients with cerebellar diseases by means of a force measuring platform using an on-line computer program which calculated sway path, sway area, antero-posterior and lateral sway components and the amount of visual stabilization. Postural ataxia was quantitatively studied in 8 patients with spinal ataxia (Friedreich's), 6 patients with vestibulocerebellar lesions, 11 patients with anterior lobe atrophy, 7 patients with hemispheral cerebellar lesions, and 9 patients with a disease affecting all parts of the cerebellum. Patients with lesions of the cerebellar hemispheres could not be separated from normals by means of posturography. Lesions of the spino-cerebellar afferents (Friedreich' ataxia) caused an omnidirectional low frequency sway with preserved visual stabilization. Patients with anterior lobe atrophy showed a predominant antero-posterior sway, often with a spontaneous high frequency body tremor around 3 Hz. Vestibulo-cerebellar lesions exhibited omnidirectional low frequency sway poorly stabilized by vision. Quantitative posturography helps to localize cerebellar lesions and allows for quantitative follow-up studies of cerebellar diseases.