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Nanohybrid photosystems have advantages in converting solar energy into electricity, while natural photosystems based solar-powered energy-storage device is still under developed. Here, we fabricate a new kind of photo-rechargeable zinc-ion hybrid capacitor (ZHC) benefiting from light-harvesting carbon dots (CDs) and natural thylakoids for realizing solar energy harvesting and storage simultaneously. Under solar light irradiation, the embedded CDs in thylakoids (CDs/Thy) can convert the less absorbed green light into highly absorbed red light for thylakoids, besides, Förster resonance energy transfer (FRET) between CDs and Thy also occurs, which facilitates the photoelectrons generation during thylakoids photosynthesis, thereby resulting in 6-fold photocurrent output in CDs/Thy hybrid photosystem, compared to pristine thylakoids. Using CDs/Thy as the photocathode in ZHCs, the photonic hybrid capacitor shows photoelectric conversion and storage features. CDs can improve the photo-charging voltage response of ZHCs to ≈1.2â V with a remarkable capacitance enhancement of 144 % under solar light. This study provides a promising strategy for designing plant-based photonic and electric device for solar energy harvesting and storage.
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The development of promising solid-state lithium batteries has been a challenging task mainly due to the poor interfacial contact and high interfacial resistance at the electrode/solid-state electrolyte (SSE) interface. Herein, we propose a strategy for introducing a class of covalent interactions with varying covalent coupling degrees at the cathode/SSE interface. This method significantly reduces interfacial impedances by strengthening the interactions between the cathode and SSE. By adjusting the covalent coupling degree from low to high, an optimal interfacial impedance of 33 Ω cm-2 was achieved, which is even lower than the interfacial impedance using liquid electrolytes (39 Ω cm-2). This work offers a fresh perspective on solving the interfacial contact problem in solid-state lithium batteries.
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Developing solid-state electrolyte with sufficient ionic conduction and flexible-intimate interface is vital to advance fast-charging solid-state lithium batteries. Solid polymer electrolyte yields the promise of interfacial compatibility, yet its critical bottleneck is how to simultaneously achieve high ionic conductivity and lithium-ion transference number. Herein, single-ion conducting network polymer electrolyte (SICNP) enabling fast charging is proposed to positively realize fast lithium-ion locomotion with both high ionic conductivity of 1.1 × 10-3 S cm-1 and lithium-ion transference number of 0.92 at room temperature. Experimental characterization and theoretical simulations demonstrate that the construction of polymer network structure for single-ion conductor not only facilitates fast hopping of lithium ions for boosting ionic kinetics, but also enables a high dissociation level of the negative charge for lithium-ion transference number close to unity. As a result, the solid-state lithium batteries constructed by coupling SICNP with lithium anodes and various cathodes (e.g., LiFePO4 , sulfur, and LiCoO2 ) display impressive high-rate cycling performance (e.g., 95% capacity retention at 5 C for 1000 cycles in LiFePO4 |SICNP|lithium cell) and fast-charging capability (e.g., being charged within 6 min and discharged over than 180 min in LiCoO2 |SICNP|lithium cell). Our study provides a prospective direction for solid-state electrolyte that meets the lithium-ion dynamics for practical fast-charging solid-state lithium batteries.
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Zn powder (Zn-P)-based anodes are considered ideal candidates for Zn-based batteries because they enable a positive synergistic integration of safety and energy density. However, Zn-P-based anodes still experience easy corrosion, uncontrolled dendrite growth, and poor mechanical strength, which restrict their further application. Herein, a mixed ionic-electronic conducting scaffold is introduced into Zn-P to successfully fabricate anti-corrosive, flexible, and dendrite-free Zn anodes using a scalable tape-casting strategy. The as-established scaffold is characterized by robust flexibility, facile scale-up synthesis methodology, and exceptional anti-corrosive characteristics, and it can effectively homogenize the Zn2+ flux during Zn plating/stripping, thus allowing stable Zn cycling. Benefiting from these comprehensive attributes, the as-prepared Zn-P-based anode provides superior electrochemical performance, including long-life cycling stability and high rate capability in practical coin and flexible pouch cells; thus, it holds great potential for developing advanced Zn-ion batteries. The findings of this study provide insights for a promising scalable pathway to fabricate highly efficient and reliable Zn-based anodes and will aid in the realization of advanced flexible energy-storage devices.
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Silicon-based anode materials with high theoretical capacity have great challenges of enormous volume expansion and poor electronic conductivity. Herein, a novel dual carbon confined SiOx/C@void@Si/C yolk-shell monodisperse nanosphere with void space have been fabricated through hydrothermal reaction, carbonization, and in-situ low-temperature aluminothermic reduction. Furthermore, the O/Si ratio and void space between SiOx/C core and Si/C shell can be effectively tuned by the length of aluminothermic reduction time. The SiOx/C core plays a role of maintaining the spherical structure and the void space can accommodate the volume expansion of Si. Moreover, the inner and outer carbons not only alleviate volume variation of SiOx and Si but also enhance the electrical conductivity of composites. Benefiting from the synergy of the double carbon and void space, the optimized VSC-14 anode affords prominent cycle stability with reversible capacity of 1094 mAh g-1 after 550 cycles at 200 mA g-1. By pre-lithiation treatment, the VSC-14 achieves an initial Coulombic efficiency of 93.27% at 200 mA g-1 and a reversible capacity of 348 mAh g-1 at 5 A g-1 after 4000 cycles. Furthermore, the pouch cell using VSC-14 anode and LiFePO4 cathode delivers a reversible capacity of 138 mAh g-1 at 0.2C. We hope this strategy can provide a scientific method to synthesis yolk-shell Si-based materials.
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Flexible aqueous battery is considered to be one of the most promising energy storage devices for powering flexible electronics. However, inferior interfacial compatibility in electrode-electrolyte interfaces and inefficient ionic channel of electrolytes usually result in potential troubles when applied in practical applications. Herein, we report a mild synthetic route to a sodium lignosulfonate-polyacrylamide hydrogel electrolyte with a high adhesiveness to achieve low electrode-electrolyte interfacial resistance and fast ionic conduction. Comprehensive experiments show that the catechol groups from sodium lignosulfonate demonstrate strong interactions with both cathode and anode materials, and thus greatly reduce the contact resistances across the electrodes. Meanwhile, the existence of sulfonate groups significantly enhances the ionic conductivity of the hydrogel electrolyte. Benefiting from this design, a low ohmic resistance of 3.8 Ω (i.e., 11.4 Ω cm2 ), a low charge transfer resistance of 22.5 Ω (i.e., 67.5 Ω cm2 ), a high ionic conductivity of 31.1 mS cm-1 as well as a 100% capacity retention upon harsh bending deformation can be realized in the flexible zinc ion battery, which are significantly superior to those in the traditional candidates. The present investigation provides new insight into addressing the interfacial issue plaguing flexible energy storage devices.
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Hidrogéis , Zinco , Fontes de Energia Elétrica , Eletrólitos , ÍonsRESUMO
In this work, a non-toxic and mild strategy was presented to efficiently fabricate porous and nitrogen-doped carbon nanosheets. Silkworm cocoon (SCs) acted as carbon source and original nitrogen source. Sodium carbonate (Na2CO3) could facilitate the SCs to expose silk protein and played a catalytic role in the subsequent activation of calcium chloride (CaCl2). Calcium chloride served as pore-making agent. The as-obtained carbon materials with protuberant porous nanosheets exhibit high specific surface area of 731 m2 g-1, rich native nitrogen-doped of 7.91 atomic %, wide pore size distribution from 0.5 to 65 nm, and thus possessing high areal specific capacitances of 34 µF cm-2 as well as excellent retention rate of 97% after 20 000 cycles at a current density of 20 A g-1 in 6 M KOH electrolyte. The assembled carbon nanosheet-based supercapacitor displays a maximum energy density of 21.06 Wh kg-1 at the power density of 225 W kg-1 in 1 M Na2SO4 electrolyte. Experimental results show that a mild and non-toxic treatment of biomass can be an effective and extensible method for preparing optimal porous carbon for electrochemical energy storage.
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Metal compounds (e.g., metal phosphides/sulfides/selenides) coupled with carbon materials have recently drawn great attraction for boosting the electrochemical performances because of their appealing synergistic effect and valuable structural stability. Despite many examples for their synthesis exist, there is still a need for a simplistic and comprehensive approach to such metal compound/carbon (MC/C) composites. Herein, an effective, facile, yet versatile strategy to produce various types of MC/C composites is presented. Key to this strategy is construction of a homogeneous triple-phase interface, which is realized by utilization of a hybrid assembly integrated with carbon, metal and sulfide (or selenide, phosphide) precursors through coupling metal cations with anion groups of a functional polymer. Such an intimately binding carbon-metal-sulfide (or selenide, phosphide) interface structure enables the successful in situ generation of MC nanoparticles uniformly encapsulated into the carbon matrix just after a one-step carbonization treatment. The present synthetic strategy provides remarkable adjustability, predictability and generality to facilely fabricate a series of MC/C composites, offering sufficient freedom to explore their unique energy storage/conversation properties. As a proof of concept, the as-prepared SnS/C composite exhibits superior lithium ion and potassium ion storage capabilities when used as anode materials for alkali-metal ion batteries. The present work provides impressive insights into the design principles for MC/C composites that are the potential materials in targeted application fields, and opens up an efficacious avenue for their facile synthesis as well.
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Aqueous zinc ion battery constitutes a safe, stable and promising next-generation energy storage device, but suffers the lack of suitable host compounds for zinc ion storage. Development of a facile way to emerging cathode materials is strongly requested toward superior electrochemical activities and practical applications. Herein, defect engineering, i.e., simultaneous introduction of nitrogen dopant and oxygen vacancy into commercial and low-cost MnO, is proposed as a positive strategy to activate the originally inert phase for kinetically propelling its zinc ion storage capability. Both experimental characterization and theoretical calculations demonstrate that the nitrogen dopant significantly improves the electric conductivity of electrochemical inert MnO. Simultaneously, the oxygen vacancy creates sufficient large inserted channels and available activated adsorption sites for zinc ions storage. These synergistic structural advantages obviously ameliorate the electrochemical performance of inert MnO. Therefore, even without any conductive agent additive, the as-prepared material shows high specific capacity, superb rate capability, prolonged cycling stability and attractive energy density, which are dramatically superior to those of the pristine MnO as well as many other host cathode materials. This work presents fresh insights on the role of defect engineering in the enhancement of the intrinsic electrochemical reactivity of inert cathode, and an effective strategy for scalable fabrication of high-performance cathode for zinc ion battery.
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As a kind of zero-dimensional material, carbon dots (CDs) have become a kind of promising novel material due to their incomparable unique physical and chemical properties. Despite the optical properties of CDs being widely studied, their surface chemical functions are rarely reported. Here we propose an interesting insight into the important role of surface chemical properties of CDs in adjusting the structure of the layered double hydroxide (LDH) and its energy storage performance. It was demonstrated that CDs with positive charge (p-CDs) not only reduce the size of the flower-like LDH through affecting the growth of LDH sheets, but also act as a structure stabilizer. After calcination, the layered double oxide (LDO) maintained the morphology of the LDH and prevented the stacking of layers. And the superiority of the composite in lithium-ion batteries (LIBs) was demonstrated. When used as an anode of LIBs, composites possess outstanding specific capacity, cycle stability and rate performance. It presents the discharge capacity of 1182 mA h g-1 and capacity retention of 94% at the current density of 100 mA g-1 after 100 cycles. Our work demonstrates the important chemical functions of CDs and expands their future applications.
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In this work, a simple and efficient method is introduced to prepare biomass-based porous carbon with excellent performance by changing the content of component (e.g., cellulose, hemicellulose, lignin, and extractives) of the raw materials. When the content of the components change, the corresponding carbon skeleton will be separated, resulting in a structure that is conducive to activation conditions. Using bagasse with fiber tubular structure as carbon precursor, the synthetic hierarchical porous carbon (BHPC-4) possesses a high specific surface area (SSA) of 3135 m2 g-1 more than the control sample (2484 m2 g-1). Benefitting from the improvement of the structure, the BHPC-4 electrode exhibits an appealing capacitance of 410.5F g-1 at 0.5 A g-1 and long-term cycling stability of 100% capacitance retention after 10,000 cycles in the 6.0 M KOH system. Furthermore, a delightful energy density of 25.6 Wh kg-1 at a 226 W kg-1 can be achieved in 1.8 V Na2SO4 aqueous symmetrical supercapacitors. This method has universal significance in preparing high-porosity and high-performance biomass-based carbon materials for various energy storage/conversion.
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Carbono , Biomassa , Capacitância Elétrica , Eletrodos , PorosidadeRESUMO
Spherical carbon materials exhibit great competence as electrode materials for electrochemical energy storage, owing to the high packing density, low surface to volume ratio, and excellent structure stability. How to utilize renewable biomass precursor by green and efficient strategy to fabricate porous carbon microspheres remains a great challenge. Herein, we report a KOH-free and sustainable strategy to fabricate porous carbon microspheres derived from cassava starch with high specific surface area, high yield, and hierarchical structure, in which potassium oxalate monohydrate (K2C2O4·H2O) and calcium chloride (CaCl2) are employed as novel activator. The green CaCl2 activator is crucial to regulate the graphitization degree, specific surface area, and porosity of the carbon microspheres for improving the electrochemical performance. The as-prepared carbon microspheres exhibit high specific surface area (1668 m2 g-1), wide pore size distribution (0.5-60 nm), high carbon content (95%), and exfoliated surface layer. The hierarchical porous carbon microspheres show high specific and areal capacitance (17.1 µF cm-2), superior rate performance, and impressive cycling stability. Moreover, the carbon microspheres based symmetric supercapacitor exhibits high capacitance and excellent cycling performance (100% after 20 000 cycles at a current density of 5 A g-1). This green and novel approach holds great promise to realize low-cost, high-efficient and scalable of renewable cassava starch-derived carbon materials for advanced supercapacitive energy storage applications.
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Facile fabrication of anode materials with low cost, good rate capability and high capacity is a critical factor towards developing sodium-ion battery for practical applications. Herein, a N, O co-doped porous carbon with uniform ultramicropores (NOPC-UM), is synthesized by an in-situ ultramicro templating strategy, and demonstrated as a high-performance sodium-ion storage material. Key to this strategy is employment of an inherent KCl as untramicro template, which leads to formation of uniform size of ultramicropores and heteroatoms (i.e., N and O) doping after high-temperature pyrolysis. The as-constructed NOPC-UM delivers a large capacity of 305 mAh g-1, accompanying with a 93% specific capacity below 1.00 V, and superior cycling stability about 100% after 4000 cycles. These attractive electrochemical performances endow NOPC-UM with impressive potential use as anode materials of sodium-ion battery.
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To engineer advanced anodes for high-rate lithium-ion battery, rational structural design with insightful understanding of rapid reaction kinetics is important and still highly desirable. In this work, a high-temperature in situ deoxidation strategy is used to propel electrochemical kinetics of NiO through incorporating an intrinsic Ni component. Both theoretical calculation and experimental study demonstrate that the Ni-NiO heterojunction significantly enhances the electronic conductivity and ion diffusion properties. Accordingly, the lithium-ion battery modified with the heterostructured Ni-NiO shows remarkably improved charge transfer efficiency and rate performance, substantially outperforming many reported NiO-based anodes. This work opens up the exploration of heterostructured metal compounds as kinetic regulators for high-rate lithium-ion battery and also enlightens the understanding of defect chemistry in propelling electrochemical reactions.
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The incorporation of functional building blocks to construct functionalized and highly porous covalent triazine frameworks (CTFs) is essential to the emerging adsorptive-involved field. Herein, a series of amide functionalized CTFs (CTF-PO71) have been synthesized using a bottom-up strategy in which pigment PO71 with an amide group is employed as a monomer under ionothermal conditions with ZnCl2 as the solvent and catalyst. The pore structure can be controlled by the amount of ZnCl2 to monomer ratio. Benefitting from the highly porous structure and amide functionalities, CTF-PO71, as a sulfur cathode host, simultaneously demonstrates physical confinement and chemical anchoring of sulfur species, thus leading to superior capacity, cycling stability, and rate capability in comparison to unfunctionalized CTF. Meanwhile, as an adsorbent of organic dye molecules, CTF-PO71 was demonstrated to exhibit strong chemical interactions with dye molecules, facilitating adsorption kinetics and thereby promoting the adsorption rate and capacity. Furthermore, the dynamic adsorption experiments of organic dyes from solutions showed selectivity/priority of CTF-PO71s for specific dye molecules.
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The ever-increasing electric vehicles and portable electronics make lithium-ion barreries (LIBs) toward high energy density, resulting in long driving range and standby times. Generally, excellent electrochemical performance can be obtained in thin electrode materials with low mass loadings (<1 mg cm-2), but it is difficult to be achieved in commercial electrodes with high mass loadings (>10 mg cm-2). In this work, we report a facile method for fabricating nitrogen doped carbon microtubes (N-CMTs) consisted of crumped carbon nanosheets for high-performance LIBs with ultrahigh mass loading, where non-tubular biomass waste (i.e., peanut dregs) is employed as the precursor. Benefiting from the hollow tubular conductive network, high graphitization, and hierarchical structure, the as-synthesized N-CMTs exhibit ultrahigh area capacity of 6.27 mAh cm-2 at a current density of 1.5 mA cm-2 with a high mass loading of 15 mg cm-2 and superior cycling stability for LIBs. Our approach provides an effective strategy for the preparation of nitrogen-doped carbon microtubes to develope high energy LIBs with high mass loading electrodes.
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Recently, SiO2 has attracted wide attention in lithium-ion batteries owing to its high theoretical capacity and low cost. However, the utilization of SiO2 is impeded by the enormous volume expansion and low electric conductivity. Although constructing SiO2/carbon composite can significantly enhance the electrochemical performance, the skillful preparation of the well-defined SiO2/carbon composite is still a remaining challenge. Here, a facile strategy of in situ coating of polydopamine is applied to synthesis of a series of core-shell structured SiO2@carbon composite nanorods with different thicknesses of carbon shells. The carbon shell uniformly coated on the surface of SiO2 nanorods significantly suppresses the volume expansion to some extent, as well as improves the electric conductivity of SiO2. Therefore, the composite nanorods exhibit a remarkable electrochemical performance as the electrode materials of lithium-ion batteries. For instance, a high and stable reversible capacity at a current density of 100 mA g-1 reaches 690 mAh g-1 and a capacity of 344.9 mAh g-1 can be achieved even at the high current density of 1000 mA g-1. In addition, excellent capacity retention reaches 95% over 100 cycles. These SiO2@carbon composite nanorods with decent electrochemical performances hold great potential for applications in lithium-ion batteries.
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An efficient self-crosslinking procedure to reasonably construct porous shells is reported for the synthesis of yolk-shell Au@microporous carbon nanospheres.
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A new kind of hollow carbon nanosphere with an ordered mesoporous shell structure is prepared and demonstrated to have improved performances in practical application areas involving fast ion transport.
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Lithium (Li) metal is considered as the ultimate anode choice for developing next-generation high-energy batteries. However, the poor tolerance against moist air and the unstable solid electrolyte interphases (SEI) induced by the intrinsic high reactivity of lithium bring series of obstacles such as the rigorous operating condition, the poor electrochemical performance, and safety anxiety of the cell, which to a large extent hinder the commercial utilization of Li metal anode. Here, an effective encapsulation strategy was reported via a facile drop-casting and a following heat-assisted cross-linking process. Benefiting from the inherent hydrophobicity and the compact micro-structure of the cross-linked poly(vinylidene-co-hexafluoropropylene) (PVDF-HFP), the as-encapsulated Li metal exhibited prominent stability toward moisture, as well corroborated by the evaluations both under the humid air at 25 °C with 30% relative humidity (RH) and pure water. Moreover, the encapsulated Li metal anode exhibits a decent electrochemical performance without substantially increasing the cell polarization due to the uniform and unblocked ion channels, which originally comes from the superior affinity of the PVDF-HFP polymer toward non-aqueous electrolyte. This work demonstrates a novel and valid encapsulation strategy for humidity-sensitive alkali metal electrodes, aiming to pave the way for the large-scale and low-cost deployment of the alkali metal-based high-energy-density batteries.