GeO2 Nanoparticles Decorated in Amorphous Carbon Nanofiber Framework as Highly Reversible Lithium Storage Anode.

Germanium oxide (GeO2) is a high theoretical capacity electrode material due to its alloying and conversion reaction. However, the actual cycling capacity is rather poor on account of suffering low electron/ion conductivity, enormous volume change and agglomeration in the repeated lithiation/delithiation process, which renders quite a low reversible electrochemical lithium storage reaction. In this work, highly amorphous GeO2 particles are uniformly distributed in the carbon nanofiber framework, and the amorphous carbon nanofiber not only improves the conduction and buffers the volume changes but also prevents active material agglomeration. As a result, the present GeO2 and carbon composite electrode exhibits highly reversible alloying and conversion processes during the whole cycling process. The two reversible electrochemical reactions are verified by differential capacity curves and cyclic voltammetry measurements during the whole cycling process. The corresponding reversible capacity is 747 mAh g-1 after 300 cycles at a current density of 0.3 A g-1. The related reversible capacities are 933, 672, 487 and 302 mAh g-1 at current densities of 0.2, 0.4, 0.8 and 1.6 A g-1, respectively. The simple strategy for the design of amorphous GeO2/carbon composites enables potential application for high-performance LIBs.

Do attachment patterns predict aggression in a context of social rejection? An executive functioning account.

People tend to respond to rejection and attack with aggression. The present research examined the modulation role of attachment patterns on provoked aggression following punishment and proposed an executive functioning account of attachment patterns' modulating influence based on the General Aggression Model. Attachment style was measured using the Experiences in Close Relationships inventory. Experiments 1a and b and 2 adopted a social rejection task and assessed subsequent unprovoked and provoked aggression with different attachment patterns. Moreover, Experiment 1b and 2 used a Stroop task to examine whether differences in provoked aggression by attachment patterns are due to the amount of executive functioning following social rejection, or after unprovoked punishment, or even before social rejection. Anxiously attached participants displayed significant more provoked aggression than securely and avoidantly attached participants in provoked aggression following unprovoked punishment in Experiments 1 and 2. Meanwhile, subsequent Stroop tests indicated anxiously attached participants experienced more executive functioning depletion after social rejection and unprovoked aggression. The present findings support the General Aggression Model and suggest that provoked aggression is predicted by attachment patterns in the context of social rejection; different provoked aggression may depend on the degree of executive functioning that individuals preserved in aggressive situations. The current study contributes to our understanding of the importance of the role of attachment patterns in modulating aggressive behavior accompanying unfair social encounters.

Low-Temperature-Processed High-Performance Pentacene OTFTs with Optimal Nd-Ti Oxynitride Mixture as Gate Dielectric.

When processed at a low temperature of 200 °C, organic thin-film transistors (OTFTs) with pentacene channel adopting high-k Neodymium-Titanium oxynitride mixtures (NdTiON) with various Ti contents as gate dielectrics are fabricated. The Ti content in the NdTiON is varied by co-sputtering a Ti target at 0 W, 10 W, 20 W and 30 W, respectively, while fixing the sputtering power of an Nd target at 45 W. High-performance OTFT is obtained for the 20 W-sputtered Ti, including a small threshold voltage of -0.71 V and high carrier mobility of 1.70 cm2/V·s. The mobility improvement for the optimal Ti content can be attributed to smoother dielectric surface and resultant larger overlying pentacene grains as reflected by Atomic Force Microscopy measurements. Moreover, this sample with the optimal Ti content shows much higher mobility than its counterpart processed at a higher temperature of 400 °C (0.8 cm2/V·s) because it has a thinner gate-dielectric/gate-electrode interlayer for stronger screening on the remote phonon scattering by the gate electrode. In addition, a high dielectric constant of around 10 is obtained for the NdTiON gate dielectric that contributes to a threshold voltage smaller than 1 V for the pentacene OTFT, implying the high potential of the Nd-Ti oxynitride in future high-performance organic devices.

Adult attachment style moderates the effect of oxytocin on neural responses to infant emotional faces.

Oxytocin (OT) is known for its positive influence on maternal motivation and behavior, however, the effects of intranasal oxytocin (IN-OT) on neural activity during the perception of infant stimuli are often inconsistent. These discrepancies further reveal the need to take into account individual differences in IN-OT research. The present study aims to examine whether the effects of IN-OT on maternal-related neural responses to infant faces were moderated by participants' attachment style. Using a between-groups, double-blind, placebo-controlled design, 65 nulliparous females were randomly assigned to groups receiving a single dose of 24 IU oxytocin or a placebo via intranasal administration. The neural responses of participants were assessed during a facial recognition task with joy, neutral, and crying infant faces. The results indicated that females with high levels of attachment anxiety exhibited decreased right amygdala activity in response to infant joy faces and decreased bilateral insula activity in response to infant crying faces following IN-OT. Meanwhile, IN-OT enhanced bilateral amygdala and left inferior orbital frontal cortex (OFC) activity in response to infant crying faces in females with high levels of attachment avoidance. In addition, some beneficial effects of IN-OT were also observed in females with low levels of attachment avoidance or anxiety. Our findings demonstrated that the beneficial effects of IN-OT on neural responses to infant faces may depend on individual differences in adult attachment style, thereby contributing to our understanding of the role of OT in maternal caregiving.

Mediating effect of psychological suzhi on the relationship between perceived social support and self-esteem.

This study examined the mediating role of psychological suzhi on the relationship between perceived social support and self-esteem in a sample of 612 Chinese secondary school students (grades 7-12, mean age 15.20 ± 1.73 years). Structural equation modeling revealed that the association between perceived social support and self-esteem was partially mediated by psychological suzhi, and perceived social support not only directly affected students' self-esteem but also indirectly affected students' self-esteem through psychological suzhi. Moreover, the mediating effect of psychological suzhi showed transgender and cross school section stability. These findings can help us understand how perceived social support affects self-esteem, from the perspective of psychological suzhi.

Mediating Effect of Dark Triad Personality Traits on the Relationship Between Parental Emotional Warmth and Aggression.

Previous research has indicated that positive parenting practices, such as parental emotional warmth, are associated with less negative outcomes in children. These negative outcomes can present during adolescence and during emerging adulthood. One negative consequence can be aggression, a problematic outcome with its own myriad consequences. The current study aimed to examine the effect of parental emotional warmth on adolescent and young adult aggression and the mediating effect of Dark Triad personality traits (Machiavellianism, psychopathy, and narcissism) on this relationship. The sample included 530 Chinese student participants who completed an online questionnaire survey: 241 adolescents aged 15 to 18 years (M = 17.24, SD = 1.00) and 289 young adults aged 19 to 23 years (M = 20.12, SD = 1.03). The results revealed that the association between parental emotional warmth and aggression was fully mediated by Machiavellianism and psychopathy, and the mediating effects of Machiavellianism and psychopathy had no age differences between adolescents and young adults. These results may clinically suggest that paying attention to parental emotional warmth, Machiavellianism, and psychopathy in adolescents and young adults could yield a better understanding of their current and continuous functioning, especially for aggression.

State attachment moderates the maternal-related neural responses to infant faces.

Adult attachment is particularly known for the modulating role of caregiving motivation and behavior. Although most studies consider attachment style relatively stable, it may also be affected by various situational factors, and these temporary fluctuations are related to meaningful behaviors. Using functional magnetic resonance imaging, the present study aims to examine whether neural responses to infant faces are moderated by participants' state attachment. The results indicated that state attachment security was positively associated with increased inferior orbitofrontal cortex (OFC) and insula activation to infant crying. State attachment anxiety was positively associated with increased insula and anterior cingulate cortex (ACC) activation to infant crying as well as enhanced cuneus activation to infant joy. In contrast, state attachment avoidance was negatively associated with amygdala activity in response to both infant joy and crying as well as insula and ACC activation in response to infant joy. Moderation analysis found that the relationship between the prediction effect of state attachment avoidance on ACC activity was gradually weakened with the attenuation of participants' trait attachment avoidance. These results demonstrate that neural responses to infant faces are moderated by individual differences in state attachment, thereby demonstrating that state attachment is an effective measure to capture the variation in maternal ability.

Intranasal oxytocin attenuates insula activity in response to dynamic angry faces.

The effects of intranasal oxytocin on amygdala activity during emotional perception are often mixed. Given that the brain is organized into networks of interconnected areas, functional connectivity might provide an effective way to further understand the oxytocin effect. The aim of the present study was to investigate whether oxytocin administration affects amygdala activity and its functional connectivity during dynamic facial expression perception. Using a between-group, double-blind, placebo-controlled design, 55 participants were randomly assigned to groups receiving a single dose of 24 IU oxytocin or a placebo via intranasal administration. An implicit emotional task was employed to investigate the effect of oxytocin on neural responses to dynamic angry, neutral, and happy facial expressions with fMRI. Participants were instructed to respond only when the inverted dynamic faces were presented. The results indicated that oxytocin attenuated activation of insula and emotional processing-related regions (e.g., ACC, thalamus, and MFG) during the viewing of dynamic angry faces. However, functional connectivity between the regions involved in the perception of dynamic angry faces was not changed following oxytocin administration. The present findings may contribute to our understanding of the anxiolytic effects of oxytocin and eventually facilitate human clinical applications.

Security priming improves attentional processing to infant emotions among insecurely attached women: The different roles of supraliminal and subliminal priming.

In two ERP experiments, we examined the attention-related mechanism involved in perceiving infant emotions following exposure to security priming. Specifically, we examined how security priming affected securely and insecurely attached women. We found that both supraliminal and subliminal security priming resulted in increased attention allocation in anxiously and avoidantly attached women but had no effect on securely attached women. Moreover, we also found that supraliminal and subliminal security priming differed in their effectiveness in increasing attention allocation among anxiously and avoidantly attached women. Supraliminal security priming were more effective for anxiously attached women, whereas subliminal security priming were more effective for avoidantly attached women. The implications of these findings and directions for future research are discussed.

Adult Attachment Affects Neural Response to Preference-Inferring in Ambiguous Scenarios: Evidence From an fMRI Study.

Humans are highly social animals, and the ability to cater to the preferences of other individuals is encouraged by society. Preference-inferring is an important aspect of the theory of mind (TOM). Many previous studies have shown that attachment style is closely related to TOM ability. However, little is known about the effects of adult attachment style on preferences inferring under different levels of certainty. Here, we investigated how adult attachment style affects neural activity underlying preferences inferred under different levels of certainty by using functional magnetic resonance imaging (fMRI). The fMRI results demonstrated that adult attachment influenced the activation of anterior insula (AI) and inferior parietal lobule (IPL) in response to ambiguous preference-inferring. More specifically, in the ambiguous preference condition, the avoidant attached groups exhibited a significantly enhanced activation than secure and anxious attached groups in left IPL; the anxious attached groups exhibited a significantly reduced activation secure attached group in left IPL. In addition, the anxious attached groups exhibited a significantly reduced activation than secure and avoidant attached groups in left AI. These results were also further confirmed by the subsequent PPI analysis. The results from current study suggest that, under ambiguous situations, the avoidant attached individuals show lower sensitivity to the preference of other individuals and need to invest more cognitive resources for preference-reasoning; while compared with avoidant attached group, the anxious attached individuals express high tolerance for uncertainty and a higher ToM proficiency. Results from the current study imply that differences in preference-inferring under ambiguous conditions associated with different levels of individual attachment may explain the differences in interpersonal interaction.

Brain correlates of adult attachment style: A voxel-based morphometry study.

Evidence from human and animal studies has shown that experiences of early attachment can influence brain development and structure. Adult attachment style develops from early attachment experiences. However, little is known about the relationship between gray matter volume and attachment style. Further, the structural bases of sex-related differences in adult attachment styles remain unknown. We used voxel-based morphometry to investigate the neuroanatomical basis underlying adult attachment styles and the structural basis of sex-related differences in adult attachment styles. Participants were 106 healthy young adults (57 women and 49 men; age, 20.8 ±â€¯1.55 years). Negative correlations were found between attachment avoidance and the volumes of the left middle temporal gyrus and the right parahippocampal gyrus, and between attachment anxiety and the right ventral anterior cingulate volume. Further analysis revealed that attachment avoidance was negatively correlated with the volume of the right middle occipital gyrus in women, but the inverse correlation was found in men. These findings suggest that differences in adult attachment styles are correlated with structural brain differences in adulthood, and that sex-related differences in adult attachment styles are associated with intrinsic structural brain differences involved in visual processing. These findings may improve our understanding of the pathophysiology of attachment-related disorder.

The Effect of Psychological Suzhi on Problem Behaviors in Chinese Adolescents: The Mediating Role of Subjective Social Status and Self-esteem.

In this study, we examined subjective social status (SSS) and self-esteem as potential mediators between the association of psychological suzhi and problem behaviors in a sample of 1271 Chinese adolescents (44.5% male, grades 7-12). The results showed that SSS and self-esteem were fully mediating the relationship between psychological suzhi and problem behaviors. Moreover, the indirect effect was stronger via self-esteem than via SSS. These findings perhaps provide insight into the preliminary effect that SSS and self-esteem underlie psychological suzhi's effect on adolescents' problem behaviors, and also are important in helping school-teachers and administrators to develop a better understanding of problem behaviors in their schools as a pre-requisite to the development of more effective behaviors management practices from the perspective of psychological suzhi. Implications and limitations in the present study have also been discussed.

The processing of body expressions during emotional scenes: the modulation role of attachment styles.

There is broad evidence indicating that contextual information influence the processing of emotional stimuli. However, attachment theory suggests that attachment styles contribute to the ways in which people perceive emotional events. To shed light on whether the processing of body expressions during different emotional scenes is modulated by attachment styles, attachment-related electrophysiological differences were measured using event-related potentials. For avoidantly attached group, our results suggested that larger N170 amplitudes were educed by neutral bodies than angry bodies, which was found only in neutral scene. Moreover, significant differences were found in P300 amplitudes in response to angry bodies compared with neutral ones only during angry scene. However, securely and anxiously attached individuals were associated with larger P300 amplitudes in response to angry bodies versus neutral ones in both emotional scenes. The current study highlights the characteristics of cognitive processing of attachment styles on body expressions during different emotional scenes, with the variation of N170 and P300 amplitude in different emotional scenes as the best example.

Adult Attachment Styles Associated with Brain Activity in Response to Infant Faces in Nulliparous Women: An Event-Related Potentials Study.

Adult attachment style is a key for understanding emotion regulation and feelings of security in human interactions as well as for the construction of the caregiving system. The caregiving system is a group of representations about affiliative behaviors, which is guided by the caregiver's sensitivity and empathy, and is mature in young adulthood. Appropriate perception and interpretation of infant emotions is a crucial component of the formation of a secure attachment relationship between infant and caregiver. As attachment styles influence the ways in which people perceive emotional information, we examined how different attachment styles associated with brain response to the perception of infant facial expressions in nulliparous females with secure, anxious, and avoidant attachment styles. The event-related potentials of 65 nulliparous females were assessed during a facial recognition task with joy, neutral, and crying infant faces. The results showed that anxiously attached females exhibited larger N170 amplitudes than those with avoidant attachment in response to all infant faces. Regarding the P300 component, securely attached females showed larger amplitudes to all infant faces in comparison with avoidantly attached females. Moreover, anxiously attached females exhibited greater amplitudes than avoidantly attached females to only crying infant faces. In conclusion, the current results provide evidence that attachment style differences are associated with brain responses to the perception of infant faces. Furthermore, these findings further separate the psychological mechanisms underlying the caregiving behavior of those with anxious and avoidant attachment from secure attachment.

Attention Modulates Neural Responses to Unpredictable Emotional Faces in Dorsolateral Prefrontal Cortex.

Unpredictability about upcoming emotional events disrupts our ability to prepare for them and ultimately results in anxiety. Here, we investigated how attention modulates the neural responses to unpredictable emotional events. Brain activity was recorded using functional magnetic resonance imaging (fMRI) while participants performed a variation of the emotional task. Behaviorally, we reported a fear-unpredictable effect and a happy-unpredictable effect. The fMRI results showed increased activity in the right dorsolateral prefrontal cortex (dlPFC) for unpredictable fear faces (Experiment 1) and decreased activity in the left dlPFC for unpredictable happy faces (Experiment 2) when these faces were unattended, probably reflecting that unpredictability amplifies the negative impact of fear faces and reduces the positive impact of happy faces. More importantly, it was found that the right dlPFC activity to unpredictable fear faces was diminished (Experiment 1) and the left dlPFC activity to unpredictable happy faces was enhanced (Experiment 2) when these faces were attended. These results suggest that attention may contribute to reducing the unpredictability about future emotional events.