RESUMEN
With the continuous rise of industrialization and agriculture, the concentration of organic contaminants such as dyes in the ecosystem has increased in subsequent years, causing major environmental contamination. Adsorption has been revealed to be a reliable and cost-effective way of eliminating organic pollutants. Biochar technology has the potential of converting trash into treasure when utilized for environmental remediation since it has numerous benefits such as the availability of diverse types of raw materials, low cost, and reusability. The potential of biochar as an adsorbent, support for catalysis, and a composite catalyst for dye degradation and mineralization is summarized in this research. It discusses its current research status in the adsorption and degradation of various dyes, incorporates the pertinent adsorption variables, encapsulates its regeneration techniques, investigates its engineering applications, and finally analyses limitations and discusses future development prospects.
Asunto(s)
Aguas Residuales , Contaminantes Químicos del Agua , Adsorción , Carbón Orgánico , Colorantes , Ecosistema , Tecnología , Textiles , Aguas Residuales/análisis , Contaminantes Químicos del Agua/análisisRESUMEN
The present study was aimed to investigate brilliant green (BG) dye sorption onto soybean straw biochar (SSB) prepared at 800 °C and further understanding the sorption mechanism. Sorption kinetic models such as pseudo-first and pseudo-second order were executed for demonstrating sorption mechanism between the dye and biochar. Results of kinetics study were fitted well to pseudo-second-order kinetic model (R2 0.997) indicating that the reaction followed chemisorption mechanism. Furthermore, the effect of various parameters like sorbent dose, dye concentration, incubation time, pH and temperature on dye sorption was also studied. The maximum dye removal percentage and sorption capacity for SSB (800 °C) within 60 min were found to be 99.73% and 73.50 mg g- 1, respectively, at pH 8 and 60 °C temperature, whereas adsorption isotherm studies showed a higher correlation coefficient values for Freundlich model (R2 0.990-0.996) followed by Langmuir model suggesting that sorption process was multilayer. The characterization of biomass and biochar was performed with the aid of analytical techniques like scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) theory, X-ray diffraction (XRD) and thermo-gravimetric analysis (TGA). FTIR analysis showed active groups on biochar surface. BET study revealed higher surface area of biochar (194.7 m2/g) than the biomass (12.84 m2/g). Besides, phyto- and cytogenotoxic studies revealed significant decrease in the toxicity of dye containing water after treating with SSB. Therefore, this study has proved the sorption potential of soybean straw biochar for BG dye and could be further considered as sustainable cost-effective strategy for treating the textile dye-contaminated wastewater.
Asunto(s)
Glycine max , Compuestos de Amonio Cuaternario/química , Contaminantes Químicos del Agua , Adsorción , Carbón Orgánico , Concentración de Iones de Hidrógeno , Cinética , TermodinámicaRESUMEN
The advancement in the treatment technology for wastewater containing recalcitrant pollutants to lower the overall cost and time of the treatment processes is the prime demand. Biochar (BC) based photocatalyst have proved their potential application in the photo-degradation of a wide range of organic pollutants. The structural and chemical properties of the BC enhance the efficacy of photocatalyst, improving its optical properties with increased stability. This review gives an overview of the progress that occurred during the last five years in BC-based photocatalyst for degradation of recalcitrant organic waste in the aqueous system, emphasizing the role of BC in the photocatalytic performance with a brief discussion regarding the various sources of BC and different strategies used to modify the BC. Further, the critical challenges are discussed, which would be confronted during the scaling up and real-time application in wastewater treatment.
Asunto(s)
Contaminantes Químicos del Agua , Purificación del Agua , Carbón Orgánico , Luz , Aguas Residuales/análisis , Contaminantes Químicos del Agua/análisisRESUMEN
In preceding years, bioactive peptides (BAPs) have piqued escalating attention owing to their multitudinous biological features. To date, many potential BAPs exhibiting anti-cancer activities have been documented; yet, obstacles such as their safety profiles and consumer acceptance continue to exist. Moreover, BAPs have been discovered to facilitate the suppression of Coronavirus Disease 2019 (CoVID-19) and maybe ideal for treating the CoVID-19 infection, as stated by published experimental findings, but their widespread knowledge is scarce. Likewise, there is a cornucopia of BAPs possessing neuroprotective effects that mend neurodegenerative diseases (NDs) by regulating gut microbiota, but they remain a subject of research interest. Additionally, a plethora of researchers have attempted next-generation approaches based on BAPs, but they need scientific attention. The text format of this critical review is organized around an overview of BAPs' versatility and diverse bio functionalities with emphasis on recent developments and novelties. The review is alienated into independent sections, which are related to either BAPs based disease management strategies or next-generation BAPs based approaches. BAPs based anti-cancer, anti-CoVID-19, and neuroprotective strategies have been explored, which may offer insights that could help the researchers and industries to find an alternate regimen against the three aforementioned fatal diseases. To the best of our knowledge, this is the first review that has systematically discussed the next-generation approaches in BAP research. Furthermore, it can be concluded that the BAPs may be optimal for the management of cancer, CoVID-19, and NDs; nevertheless, experimental and preclinical studies are crucial to validate their therapeutic benefits.