RESUMO
A residue-free transfer method for graphene is proposed in this study, especially for the fabrication of suspended structures. Using perforated polymer templates, graphene can be precisely transferred onto the specific position in the perforated target SiO2/Si substrates without the need for polymer removal and the subsequent thermal annealing process. The surface of the transferred graphene by the proposed method was analyzed and corroborated via Raman spectroscopy, Fourier transform infrared spectroscopy, transmission electron microscopy. The results of these analyses suggest that the graphene surface has no polymeric residues resulting from the transfer process. The proposed method provides a powerful approach for the transfer of 2D materials and it enables the exploitation of their suspended structures for device applications as well as the physical characterizations without worry on the effect of contaminants.
RESUMO
Surface-enhanced Raman spectroscopy (SERS) demands reliable, high-enhancement substrates in order to be used in different fields of application. Here we introduce freestanding porous gold membranes (PAuM) as easy-to-produce, scalable, mechanically stable, and effective SERS substrates. We fabricate large-scale sub-30 nm thick PAuM that form freestanding membranes with varying morphologies depending on the nominal gold thickness. These PAuM are mechanically stable for pressures up to more than 3 bar and exhibit surface-enhanced Raman scattering with local enhancement factors from 104 to 105, which we demonstrate by wavelength-dependent and spatially resolved Raman measurements using graphene as a local Raman probe. Numerical simulations reveal that the enhancement arises from individual, nanoscale pores in the membrane acting as optical slot antennas. Our PAuM are mechanically stable, provide robust SERS enhancement for excitation power densities up to 106 W cm-2, and may find use as a building block in SERS-based sensing applications.
RESUMO
Vibration sensors are essential for signal acquisition, motion measuring, and structural health evaluations in civil and industrial applications. However, the mechanical brittleness and complicated installation process of micro-electromechanical system vibration sensors block their applications in wearable devices and human-machine interaction. The development of flexible vibration sensors satisfying the requirements of good flexibility, high sensitivity, and the ability to attach conformably on curved critical components is highly demanded but still remains a challenge. Here, we demonstrate a highly sensitive and fully flexible vibration sensor with a channel-crack-designed suspended sensing membrane for high dynamic vibration and acceleration monitoring. The flexible sensor is designed as a suspended vibration membrane structure by bonding a channel-crack-sensing membrane on a cavity substrate, of which the suspended sensing membrane can freely vibrate out of plane under external vibration. By inducing the cracks to be generated in the embedded multiwalled carbon nanotube channels and fully cracked across the conducting routes, the suspended vibration membrane shows high sensitivity, good reproducibility, and robust sensing stability. The resultant vibration sensor demonstrates an ultrawide frequency vibration response range from 0.1 to 20,000 Hz and exhibits the ability to respond to acceleration vibration with a broad response of 0.24-100 m/s2. The high sensitivity, wide bandwidth, and fully flexible format of the vibration sensor enable it to be directly attached on human bodies and curvilinear surfaces to conduct in situ vibration sensing, which was demonstrated by motion detection, voice identification, and the vibration monitoring of mechanical equipment.