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J. forensic med ; Fa yi xue za zhi;(6): 437-439, 2009.
Article in Chinese | WPRIM | ID: wpr-983521

ABSTRACT

OBJECTIVE@#To establish a new high performance liquid chromatography (HPLC) method for determining the concentration of cefazolin, cefradine, cefoperazone and cefotaxime in blood and urine, as well as to investigate its applicability.@*METHODS@#Protein in blood and urine was precipitated directly by acetonitrile with acetanilide was used as the internal standard using Agilent Zorbax SB-Aq column (250 mm x 4.6 mm, 5 microm). The mixed solvents of water (triethylamine 0.12%, acetic acid 0.12%) and acetonitrile were used as the mobile phase to separate cephalosporins using gradient elution method at 1 mL/min (flow rate) and 254 nm (detection wavelength).@*RESULTS@#The working curve of four cephalosporins showed a good correlation (r = 0.9993), with the detection limit up to 0.01 microg/mL. The recovery rate was more than 81.2%.@*CONCLUSION@#This method is fast, easy and accurate. It is suitable for biological analysis of the 4 cephalosporins of the blood and urine in practical cases.


Subject(s)
Adult , Humans , Male , Anti-Bacterial Agents/urine , Cefazolin/urine , Cefoperazone/urine , Cefotaxime/urine , Cephalosporins/urine , Cephradine/urine , Chromatography, High Pressure Liquid/methods , Forensic Toxicology , Sensitivity and Specificity , Specimen Handling
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